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Title: Elucidations of Structure and Molecular Dynamics of Complex Polymers by State-of-the-Art Solid-State NMR Spectroscopy
Solid-state nuclear magnetic resonance (ssNMR) has been playing an indispensable role in revealing the interplay of structure and molecular dynamics in polymers at different states. In this Perspective, we first provide an overview about the fundamental spin interactions in ssNMR and then highlight some recent progress on sensitivity-enhanced ssNMR spectroscopy and in situ NMR. Moreover, we highlight ssNMR applications in the field of polymer crystallization, molecular dynamics, chemical reactions, supramolecular polymers, energy materials, and so on. Finally, our personal perspective is given on the future development at the crossroad of ssNMR and polymer science.  more » « less
Award ID(s):
2004393
PAR ID:
10537915
Author(s) / Creator(s):
; ;
Publisher / Repository:
American Chemical Society
Date Published:
Journal Name:
Macromolecules
Volume:
57
Issue:
5
ISSN:
0024-9297
Page Range / eLocation ID:
1893 to 1918
Subject(s) / Keyword(s):
solid state NMR, polymer science, polymer engineering,
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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