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Title: Crystal structure of (6,9-diacetyl-5,10,15,20-tetraphenylsecochlorinato)nickel(II)
Title compound1Ni, [Ni(C46H32N4O2)], a secochlorin nickel complex, was prepared by diol cleavage of a precursortrans-dihydroxydimethylchlorin. Two crystallographically independent molecules in the structure are related by pseudo-A lattice centering, with molecules differing mainly by a rotation of one of the acetyls and an adjacent phenyl groups. The two molecules have virtually identical conformations characterized by noticeable in-plane deformation in the A1gmode and a prominent out-of-plane deformation in the B1u(ruffling) mode. Directional interactions between molecules are scarce, limited to just a few C—H...O contacts, and intermolecular interactions are mostly dispersive in nature.  more » « less
Award ID(s):
1800361
PAR ID:
10539769
Author(s) / Creator(s):
; ;
Publisher / Repository:
IUCR
Date Published:
Journal Name:
Acta Crystallographica Section E Crystallographic Communications
Volume:
80
Issue:
6
ISSN:
2056-9890
Page Range / eLocation ID:
649 to 653
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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