Abstract Polyatomic molecules have been identified as sensitive probes of charge-parity violating and parity violating physics beyond the Standard Model (BSM). For example, many linear triatomic molecules are both laser-coolable and have parity doublets in the ground electronic state arising from the bending vibration, both features that can greatly aid BSM searches. Understanding the state is a crucial prerequisite to precision measurements with linear polyatomic molecules. Here, we characterize the fundamental bending vibration of YbOH using high-resolution optical spectroscopy on the nominally forbidden  transition at 588 nm. We assign 39 transitions originating from the lowest rotational levels of the state, and accurately model the state’s structure with an effective Hamiltonian using best-fit parameters. Additionally, we perform Stark and Zeeman spectroscopy on the state and fit the molecule-frame dipole moment to Dand the effective electrong-factor to . Further, we use an empirical model to explain observed anomalous line intensities in terms of interference from spin–orbit and vibronic perturbations in the excited state. Our work is an essential step toward searches for BSM physics in YbOH and other linear polyatomic molecules. 
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                            An optical atomic clock using 4DJ states of rubidium
                        
                    
    
            Abstract We analyze an optical atomic clock using two-photon transitions in rubidium. Four one- and two-color excitation schemes to probe the and fine-structure states are considered in detail. We compare key characteristics of Rb and two-photon clocks. The clock features a high signal-to-noise ratio due to two-photon decay at favorable wavelengths, low dc electric and magnetic susceptibilities, and minimal black-body shifts. Ac Stark shifts from the clock interrogation lasers are compensated by two-color Rabi-frequency matching. We identify a ‘magic’ wavelength near 1060 nm, which allows for in-trap, Doppler-free clock-transition interrogation with lattice-trapped cold atoms. From our analysis of clock statistics and systematics, we project a quantum-noise-limited relative clock stability at the -level, with integration timeτin seconds, and a relative accuracy of . We describe a potential architecture for implementing the proposed clock using a single telecom clock laser at 1550 nm, which is conducive to optical communication and long-distance clock comparisons. Our work could be of interest in efforts to realize small and portable Rb clocks and in high-precision measurements of atomic properties of Rb -states. 
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                            - Award ID(s):
- 2110049
- PAR ID:
- 10542883
- Publisher / Repository:
- IOP Publishing
- Date Published:
- Journal Name:
- Quantum Science and Technology
- Volume:
- 9
- Issue:
- 4
- ISSN:
- 2058-9565
- Format(s):
- Medium: X Size: Article No. 045046
- Size(s):
- Article No. 045046
- Sponsoring Org:
- National Science Foundation
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