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Title: A Physics-based Model Assisted by Machine-Learning for Sodium-ion Batteries with both Liquid and Solid Electrolytes
In the absence of experimental data of fully developed hierarchical 3D sodium solid-state batteries, we developed an improved continuum model by relying on Machine Learning-assisted parameter fitting to uncover the intrinsic material properties that can be transferred into different battery models. The electrochemical system simulated has sodium metal P2-type Na2/3[Ni1/3Fe1/12Mn7/12]O2(NNFMO) as the cathode material, paired with two types of electrolytes viz, the organic liquid electrolyte and a solid polymer electrolyte. We implemented a 1D continuum model in COMSOL to suit both liquid and solid electrolytes, then used a Gaussian Process Regressor to fit and evaluate the electrochemical parameters in both battery systems. To enhance the generalizability of our model, the liquid cell and solid cell models share the same OCV input for the cathode materials. The resulting parameters are well aligned with their physical meaning and literature values. The continuum model is then used to understand the effect of increasing the thickness of the cathode and current density by analyzing the cathode utilization, and the overpotentials arising from transport and charge transfer. This 1D model and the parameter set are ready to be used in a 3D battery architecture design.  more » « less
Award ID(s):
2134715
PAR ID:
10543217
Author(s) / Creator(s):
; ; ; ; ;
Publisher / Repository:
ECS
Date Published:
Journal Name:
Journal of The Electrochemical Society
Volume:
171
Issue:
6
ISSN:
0013-4651
Page Range / eLocation ID:
060516
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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