The detection of mid-infrared (MIR) light is technologically important for applications such as night vision, imaging, sensing, and thermal metrology. Traditional MIR photodetectors either require cryogenic cooling or have sophisticated device structures involving complex nanofabrication. Here, we conceive spectrally tunable MIR detection by using two-dimensional metal halide perovskites (2D-MHPs) as the critical building block. Leveraging the ultralow cross-plane thermal conductivity and strong temperature-dependent excitonic resonances of 2D-MHPs, we demonstrate ambient-temperature, all-optical detection of MIR light with sensitivity down to 1 nanowatt per square micrometer, using plastic substrates. Through the adoption of membrane-based structures and a photonic enhancement strategy unique to our all-optical detection modality, we further improved the sensitivity to sub–10 picowatt-per-square-micrometer levels. The detection covers the mid-wave infrared regime from 2 to 4.5 micrometers and extends to the long-wave infrared wavelength at 10.6 micrometers, with wavelength-independent sensitivity response. Our work opens a pathway to alternative types of solution-processable, long-wavelength thermal detectors for molecular sensing, environmental monitoring, and thermal imaging.
more »
« less
Mid-Infrared Spectrometer Based on Tunable Photoresponses in Pdse 2
Mid-infrared (mid-IR) photodetection is important for various applications, including biomedical diagnostics, security, chemical identification, and free-spacing optical communications. However, conventional “photon” mid-IR photodetectors require liquid nitrogen cooling (i.e., MCT). Furthermore, acquiring mid-IR spectra usually involves a complex and expensive Fourier Transform Infrared spectrometer, a tabletop instrument consisting of a meter-long interferometer and MCT detectors, which is not suitable for mobile and compact device applications. In this work, we present tunable photoresponsivity in the mid-IR wavelength in palladium diselenide (PdSe2) – molybdenum disulfide (MoS2) heterostructure field-effect transistors (FETs), operating at room temperature. Furthermore, we applied a tunable membrane cavity to modulate the Fabry–Pérot resonance to modulate the absorption spectrum of the device layer. We used a robust polyetherimide (PEI) membrane with CVD-grown graphene to electrically tune the membrane structure. For the next step, we will integrate the PdSe2-based photodetector and tunable membrane to increase detection sensitivity and spectrum tunability to realize the ‘learning’-based spectroscopy.
more »
« less
- Award ID(s):
- 2150561
- PAR ID:
- 10545000
- Publisher / Repository:
- World Scientific Publishing Company
- Date Published:
- Journal Name:
- International Journal of High Speed Electronics and Systems
- Volume:
- 33
- Issue:
- 02n03
- ISSN:
- 0129-1564
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Abstract In recent years, the excitation of surface phonon polaritons (SPhPs) in van der Waals materials received wide attention from the nanophotonics community. Alpha-phase Molybdenum trioxide (α-MoO3), a naturally occurring biaxial hyperbolic crystal, emerged as a promising polaritonic material due to its ability to support SPhPs for three orthogonal directions at different wavelength bands (range 10–20μm). Here, we report on the fabrication, structural, morphological, and optical IR characterization of large-area (over 1 cm2size)α-MoO3polycrystalline film deposited on fused silica substrates by pulsed laser deposition. Due to the random grain distribution, the thin film does not display any optical anisotropy at normal incidence. However, the proposed fabrication method allows us to achieve a singleα-phase, preserving the typical strong dispersion related to the phononic response ofα-MoO3flakes. Remarkable spectral properties of interest for IR photonics applications are reported. For instance, a polarization-tunable reflection peak at 1006 cm−1with a dynamic range of ΔR= 0.3 and a resonanceQ-factor as high as 53 is observed at 45° angle of incidence. Additionally, we report the fulfillment of an impedance matching condition with the SiO2substrate leading to a polarization-independent almost perfect absorption condition (R< 0.01) at 972 cm−1which is maintained for a broad angle of incidence. In this framework our findings appear extremely promising for the further development of mid-IR lithography-free, scalable films, for efficient and large-scale sensors, filters, thermal emitters, and label-free biochemical sensing devices operating in the free space, using far-field detection setups.more » « less
-
Mid-infrared (mid-IR) absorption spectroscopy based on integrated photonic circuits has shown great promise in trace-gas sensing applications in which the mid-IR radiation directly interacts with the targeted analyte. In this paper, considering monolithic integrated circuits with quantum cascade lasers (QCLs) and quantum cascade detectors (QCDs), the InGaAs−InP platform is chosen to fabricate passive waveguide gas sensing devices. Fully suspended InGaAs waveguide devices with holey photonic crystal waveguides (HPCWs) and subwavelength grating cladding waveguides (SWWs) are designed and fabricated for mid-infrared sensing at λ = 6.15 μm in the low-index contrast InGaAs−InP platform. We experimentally detect 5 ppm ammonia with a 1 mm long suspended HPCW and separately with a 3 mm long suspended SWW, with propagation losses of 39.1 and 4.1 dB/cm, respectively. Furthermore, based on the Beer−Lambert infrared absorption law and the experimental results of discrete components, we estimated the minimum detectable gas concentration of 84 ppb from a QCL/QCD integrated SWW sensor. To the best of our knowledge, this is the first demonstration of suspended InGaAs membrane waveguides in the InGaAs−InP platform at such a long wavelength with gas sensing results. Also, this result emphasizes the advantage of SWWs to reduce the total transmission loss and the size of the fully integrated device’s footprint by virtue of its low propagation loss and TM mode compatibility in comparison to HPCWs. This study enables the possibility of monolithic integration of quantum cascade devices with TM polarized characteristics and passive waveguide sensing devices for on-chip mid-IR absorption spectroscopy.more » « less
-
Abstract Chalcogenide optical phase change materials (PCMs) have garnered significant interest for their growing applications in programmable photonics, optical analog computing, active metasurfaces, and beyond. Limited endurance or cycling lifetime is however increasingly becoming a bottleneck toward their practical deployment for these applications. To address this issue, a systematic study elucidating the cycling failure mechanisms of Ge2Sb2Se4Te (GSST) is performed, a common optical PCM tailored for infrared photonic applications, in an electrothermal switching configuration commensurate with their applications in on‐chip photonic devices. Further a set of design rules building on insights into the failure mechanisms is proposed, and successfully implemented them to boost the endurance of the Ge2Sb2Se4Te (GSST) device to over 67 000 cycles.more » « less
-
Abstract Ultraluminous infrared galaxies are powered by a combination of rapid star formation and active galactic nucleus (AGN) emission, but their relative importance is not always observationally clear. We study the galactic continuum spectrum of a cosmologically simulated ∼4 × 1010M⊙stellar mass starburst galaxy at redshiftz ∼ 4.4 that refines down to resolve beyond the dust sublimation boundary of its super-Eddington-accreting ∼107M⊙supermassive black hole. We find that this system resembles the rare class of hot dust-obscured galaxy (Hot DOG), with a roughly flat (inνFν) IR emission spectrum that sharply drops off at wavelengths ≲5μm. Our system also matches with the observational properties of many Hot DOGs, including undergoing multiple galaxy mergers and being the most massive galaxy within a dense cosmological environment. The distinctive Hot DOG spectral shape in our system is caused by AGN-heated mid-IR warm dust, predominately starburst-heated far-IR cold dust, and a steep near- to mid-IR cutoff caused by strong absorption in the dense ISM of the galactic nucleus, rather than the dust torus itself. This system is lower luminosity (LIR ∼ 2 × 1012L⊙) than those detected by the WISE survey at similar redshifts, but will be a prime target for future far-IR surveys such as PRIMA. Our results show that Hot DOGs can naturally result as a transitional phase during rapid AGN accretion, but before significant AGN-driven outflows clear optically thin paths.more » « less
An official website of the United States government

