We investigate the behavior of higher-form symmetries at variousquantum phase transitions. We consider discrete 1-form symmetries, whichcan be either part of the generalized concept “categorical symmetry”(labelled as \tilde{Z}_N^{(1)} Z ̃ N ( 1 ) )introduced recently, or an explicit Z_N^{(1)} Z N ( 1 ) 1-form symmetry. We demonstrate that for many quantum phase transitionsinvolving a Z_N^{(1)} Z N ( 1 ) or \tilde{Z}_N^{(1)} Z ̃ N ( 1 ) symmetry, the following expectation value \langle \left( O_\mathcal{C}\right)^2 \rangle ⟨ ( O 𝒞 ) 2 ⟩ takes the form \langle \left( \log O_\mathcal{C} \right)^2 \rangle \sim - \frac{A}{\epsilon} P + b \log P ⟨ ( log O 𝒞 ) 2 ⟩ ∼ − A ϵ P + b log P , where O_\mathcal{C} O 𝒞 is an operator defined associated with loop \mathcal{C} 𝒞 (or its interior \mathcal{A} 𝒜 ),which reduces to the Wilson loop operator for cases with an explicit Z_N^{(1)} Z N ( 1 ) 1-form symmetry. P P is the perimeter of \mathcal{C} 𝒞 ,and the b \log P b log P term arises from the sharp corners of the loop \mathcal{C} 𝒞 ,which is consistent with recent numerics on a particular example. b b is a universal microscopic-independent number, which in (2+1)d ( 2 + 1 ) d is related to the universal conductivity at the quantum phasetransition. b b can be computed exactly for certain transitions using the dualitiesbetween (2+1)d ( 2 + 1 ) d conformal field theories developed in recent years. We also compute the"strange correlator" of O_\mathcal{C} O 𝒞 : S_{\mathcal{C}} = \langle 0 | O_\mathcal{C} | 1 \rangle / \langle 0 | 1 \rangle S 𝒞 = ⟨ 0 | O 𝒞 | 1 ⟩ / ⟨ 0 | 1 ⟩ where |0\rangle | 0 ⟩ and |1\rangle | 1 ⟩ are many-body states with different topological nature.
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Formal Dearomative Hydroamination of 2-Arylphenols
An acid-promoted dearomative rearrangement of O-arylhydroxylamines affords 2-aminocyclohexadien-1-ones, which can in turn be reductively quenched for the synthesis of trans-aminoalcohols on a cyclohexadiene core. This method serves as an efficient entry to the pharmaceutically relevant 1-arylcyclohexylamine scaffold in two steps (one purification) from commercially available or readily prepared 2-arylphenols.
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- Award ID(s):
- 2117287
- PAR ID:
- 10549168
- Publisher / Repository:
- American Chemical Society
- Date Published:
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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