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1. Seasonally Variable Aquifer Discharge and Cooler Climate in Bermuda During the Last Interglacial Revealed by Subannual Clumped Isotope Analysis

   https://doi.org/10.1029/2020PA004145  

   Zhang, Jade Z.; Petersen, Sierra V.; Winkelstern, Ian Z.; Lohmann, Kyger C. (May 2021, Paleoceanography and Paleoclimatology)

   Abstract Faunal analog reconstructions suggest that Last Interglacial (MIS 5e) sea surface temperatures were cooler around Bermuda and in the Caribbean than modern climate. Here we describe new and revised clumped isotope measurements ofCittarium picafossil shells supporting previous findings of cooler than modern temperatures in Bermuda during the Last Interglacial. We resolve temperature and δ¹⁸O_wdifferences between two closely located and apparently coeval sites described in Winkelstern et al. (2017),https://doi.org/10.1002/2016pa003014through reprocessing raw isotopic data with the updated Brand/IUPAC parameters. New subannual‐resolution clumped isotope data reveal large variations in δ¹⁸O_wout of phase with seasonal temperature changes (i.e., lower δ¹⁸O_wvalues in winter). Supported by modern δ¹⁸O_wmeasurements identifying similar processes occurring today, we suggest past variations in coastal δ¹⁸O_wwere driven by seasonally variable freshwater discharge from a subterranean aquifer beneath the island. Taken together, our results emphasize the importance of δ¹⁸O_win controlling carbonate δ¹⁸O, and suggest that typical assumptions of constant δ¹⁸O_wshould be made cautiously in nearshore settings and can contribute to less accurate reconstructions of paleotemperature. 

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2. Looking upstream with clumped and triple oxygen isotopes of estuarine oyster shells in the early Eocene of California, USA

   https://doi.org/10.1130/G49634.1  

   Kelson, Julia R.; Petersen, Sierra V.; Niemi, Nathan A.; Passey, Benjamin H.; Curley, Allison N. (April 2022, Geology)

   The δ18O of carbonate minerals that formed at Earth’s surface is widely used to investigate paleoclimates and paleo-elevations. However, a multitude of hydrologic processes can affect δ18O values, including mixing, evaporation, distillation of parent waters, and carbonate growth temperatures. We combined traditional carbon and oxygen isotope analyses with clumped (Δ47) and triple oxygen isotopes (Δ′17O) analyses in oyster shells (Acutostrea idriaensis) of the Goler Formation in southern California (USA) to obtain insights into surface temperatures and δ18O values of meteoric waters during the early Eocene hothouse climate. The Δ47-derived temperatures ranged from 9 °C to 20 °C. We found a correlation between the δ18O of growth water (δ18Ogw) (calculated using Δ47 temperatures and δ18O of carbonate) and the δ13C values of shells. The Δ′17O values of shell growth waters (0.006‰–0.013‰ relative to Vienna standard mean ocean water–standard light Antarctic precipitation [VSMOW-SLAP]) calculated from Δ′17O of carbonate (–0.087‰ to –0.078‰ VSMOW-SLAP) were lower than typical meteoric waters. These isotopic compositions are consistent with oyster habitation in an estuary. We present a new triple oxygen isotope mixing model to estimate the δ18O value of freshwater supplying the estuary (δ18Ofw). The reconstructed δ18Ofw of –11.3‰ to –14.7‰ (VSMOW) is significantly lower than the δ18Ogw of –4.4‰ to –9.9‰ that would have been calculated using “only” Δ47 and δ18O values of carbonate. This δ18Ofw estimate supports paleogeographic reconstructions of a Paleogene river fed by high-elevation catchments of the paleo–southern Sierra Nevada. Our study highlights the potential for paired Δ47 and Δ′17O analyses to improve reconstructions of meteoric water δ18O, with implications for understanding ancient climates and elevations. 

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3. Orbital‐ to millennial‐scale variation of the speleothem δ18O record during Marine Isotope Stages 5 to 3 on the southeast Chinese Loess Plateau and its climatic and environmental implications

   https://doi.org/10.1002/jqs.3489  

   CAI, YANJUN; CHENG, HAI; CHENG, XING; SHI, ZHENGGUO; LU, YANBIN; MA, LE; PÉREZ‐MEJÍAS, CARLOS; ZHANG, HAIWEI; WEI, YINGYING; XUE, GANG; et al (April 2023, Journal of Quaternary Science)

   The Chinese Loess Plateau (CLP) is located in northern China, a region climatically dominated by the East Asian monsoon. Speleothem records from this region are crucial to fully understand the variability of the East Asian summer monsoon (EASM) and reconcile the disparity seen between loess records and speleothem δ18O records for the EASM. Here, we present an absolutely dated stalagmite isotope record spanning most of Marine Isotope Stage (MIS) 5 to MIS 3 from Xiaotian Cave, southeast CLP. The Xiaotian speleothem δ18O record is dominated by precessional variations and punctuated by notable millennial‐scale oscillations; in particular, the δ18O values in MIS 5e, 5c and 5a were in the same range, consistent with other speleothem δ18O records from the EASM region within quoted errors, verifying the difference between speleothem δ18O and loess records (e.g. magnetic susceptibility) and the proposition that those two archives may record different aspects of the EASM changes. The similar values in MIS 5e, 5c and 5a observed from the speleothem δ18O records in EASM regions, incompatible with the relatively higher North Hemisphere Summer Insolation (NHSI) during MIS 5e, were probably caused by an equivalent or even increased contribution of 18O‐enriched moisture from the South China Sea and North Pacific, implying that an El Niño‐like state existed during MIS 5e. The Xiaotian δ18O values increased abruptly at ~121.7 thousand years (kyr) before the present (bp, present refers to ad 1950), consistent with the trend seen in previously reported Chinese speleothem δ18O records, indicating an abrupt regime shift in atmospheric circulations or hydroclimate conditions in the Asian monsoon systems. It cannot be definitely ruled out that an increase in sea ice extent in the northern North Atlantic, responding to a decrease of NHSI, reached a threshold to have led to abrupt changes in the Asian summer monsoon (ASM) through rapid shifts in the position of circulation of the westerlies and/or in the position of Intertropical Convergence Zone (ITCZ). Here, we hypothesized that sea surface cooling in the tropical Indian and Pacific Ocean caused by the decreased summer insolation reached a threshold that eventually resulted in an abrupt shift to more positive precipitation δ18O, either through weakened convection over the tropical ocean, or through abrupt shifts in moisture transport and cycling of tropical moisture sources for the ASM. The Xiaotian speleothem δ18O record also shows centennial‐scale variability with amplitude up to 3‰ within MIS 5e. These changes are similar to variations recorded by the speleothem δ18O record from Tianmen Cave on the south‐central Tibetan Plateau and Shangxiaofeng Cave in Shandong Province, northern China, suggesting a heightened sensitivity of precipitation δ18O to climate changes at the marginal zone of the ASM even during the warm and humid MIS 5e interglacial. Climatic oscillations during MIS 5e appear to be comparable to those typical of the Holocene, implying rather unstable climate conditions during the Last Interglacial. 

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4. Douglas Fir Multiproxy Tree-Ring Data Glimpse MIS 5 Environment in the U.S. Pacific Northwest

   https://doi.org/10.3390/f13122161  

   Panyushkina, Irina P.; Leavitt, Steven W.; Meko, David M.; Black, Bryan A.; Jull, A. J.; Van de Water, Peter; Squire, Joe; Testa, Nicholas R. (December 2022, Forests)

   Proxy records from the late Quaternary help in understanding climate variability on extended time scales. An ancient landslide deposit in Oregon U.S.A. preserved large logs from Douglas fir trees (Pseudotsuga menziesii (Mirb.) Franco) and afforded an opportunity to explore the response of tree growth to climate on annual and decadal scales. High-precision radiocarbon dating indicates an age exceeding 63 ka, i.e., the trees grew within the generally cool Marine Isotope Stage 5 (MIS 5), likely during a warmer interval optimal for Douglas fir establishment. This would include the prolonged warm MIS 5e (ca. 110–130 ka), corresponding approximately to the Eemian interglacial, which was warm like the current Holocene interglacial. A 297-year tree-ring width chronology from 12 Douglas fir logs and 227-year tree-ring δ13C and δ18O records are analyzed with spectral and wavelet analysis. Variance of the ancient rings is consistent with modern Douglas fir growth sensitive to moisture and ecological disturbances. Spectra of ancient and modern chronologies are dominated by low frequencies with significant spectral peaks appearing at high frequencies (2.1–4 years) and cyclic behavior transient over centuries. It is conceivable that the O-isotopes track moisture and that C-isotopes track temperature or sunlight. The findings illustrate the challenges in assessing the response of ancient tree-ring properties to late Quaternary climate variability. 

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5. Controls on range shifts of coastal Californian bivalves during the peak of the last interglacial and baseline predictions for today

   https://doi.org/10.1017/pab.2020.43  

   Orzechowski, Emily A.; Finnegan, Seth (August 2021, Paleobiology)

   Abstract As the most recent time in Earth history when global temperatures were warmer than at present, the peak of the last interglacial (Marine Isotope Substage [MIS] 5e; ~120,000 years ago) can serve as a pre-anthropogenic baseline for a warmer near-future world. Here we use a new compilation of 22 fossil localities in California that have been reliably dated to MIS 5e to establish baseline expectations for contemporary bivalve species movements by identifying and analyzing bivalve species with “extralimital” ranges, that is, species that occupied the California region during MIS 5e but are now restricted to adjacent regions. We find that 15% of species ( n = 142) found in MIS 5e localities have extralimital ranges and currently occupy warmer waters to the south of the California region. The majority of extralimital occurrences occur in paleo-embayments, suggesting that these sheltered habitats were more suitable habitats for warm-water species than exposed coasts during the MIS 5e. We further find that extralimital species now tend to occur in cooler, more seasonally productive coastal waters and to occupy more offshore islands when compared with the broader species pool immediately south of California. These findings suggest that high dispersal potential and preexisting tolerances to environmental conditions similar to California's comparatively cool and seasonally productive environments may have enabled extralimital bivalves to colonize the California region during MIS 5e. 

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