An official website of the United States government
Abstract Temperate exoplanets between the sizes of Earth and Neptune, known as “sub-Neptunes,” have emerged as intriguing targets for astrobiology. It is unknown whether these planets resemble Earth-like terrestrial worlds with a habitable surface, Neptune-like giant planets with deep atmospheres and no habitable surface, or something exotic in between. Recent JWST transmission spectroscopy observations of the canonical sub-Neptune, K2-18 b, revealed ~1% CH4, ~1% CO2, and a nondetection of CO in the atmosphere. While previous studies proposed that the observed atmospheric composition could help constrain the lower atmosphere's conditions and determine the interior structure of sub-Neptunes like K2-18 b, the possible interactions between the atmosphere and a hot, supercritical water ocean at its base remain unexplored. In this work, we investigate whether a global supercritical water ocean, resembling a planetary-scale hydrothermal system, can explain these observations on K2-18 b–like sub-Neptunes through equilibrium aqueous geochemical calculations. We find that the observed atmospheric CH4/CO2ratio implies a minimum ocean temperature of ~710 K, whereas the corresponding CO/CO2ratio allows ocean temperatures up to ~1070 K. These results indicate that a global supercritical water ocean on K2-18 b is plausible. While life cannot survive in such an ocean, this work represents the first step toward understanding how a global supercritical water ocean may influence observable atmospheric characteristics on volatile-rich sub-Neptunes. Future observations with better-constrained CO and NH3mixing ratios could further help distinguish between possible interior compositions of K2-18 b.
more »
« less
Toward a Self-consistent Evaluation of Gas Dwarf Scenarios for Temperate Sub-Neptunes
Abstract The recent JWST detections of carbon-bearing molecules in a habitable-zone sub-Neptune have opened a new era in the study of low-mass exoplanets. The sub-Neptune regime spans a wide diversity of planetary interiors and atmospheres not witnessed in the solar system, including mini-Neptunes, super-Earths, and water worlds. Recent works have investigated the possibility of gas dwarfs, with rocky interiors and thick H2-rich atmospheres, to explain aspects of the sub-Neptune population, including the radius valley. Interactions between the H2-rich envelope and a potential magma ocean may lead to observable atmospheric signatures. We report a coupled interior-atmosphere modeling framework for gas dwarfs to investigate the plausibility of magma oceans on such planets and their observable diagnostics. We find that the surface–atmosphere interactions and atmospheric composition are sensitive to a wide range of parameters, including the atmospheric and internal structure, mineral composition, volatile solubility and atmospheric chemistry. While magma oceans are typically associated with high-temperature rocky planets, we assess if such conditions may be admissible and observable for temperate sub-Neptunes. We find that a holistic modeling approach is required for this purpose and to avoid unphysical model solutions. Using our model framework, we consider the habitable-zone sub-Neptune K2-18 b as a case study and find that its observed atmospheric composition is incompatible with a magma ocean scenario. We identify key atmospheric molecular and elemental diagnostics, including the abundances of CO2, CO, NH3, and, potentially, S-bearing species. Our study also underscores the need for fundamental material properties for accurate modeling of such planets.
more »
« less
- Award ID(s):
- 2242946
- PAR ID:
- 10552316
- Publisher / Repository:
- DOI PREFIX: 10.3847
- Date Published:
- Journal Name:
- The Astrophysical Journal
- Volume:
- 975
- Issue:
- 1
- ISSN:
- 0004-637X
- Format(s):
- Medium: X Size: Article No. 101
- Size(s):
- Article No. 101
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Abstract We investigate the consequences of nonideal chemical interaction between silicate and overlying hydrogen-rich envelopes for rocky planets using basic tenets of phase equilibria. Based on our current understanding of the temperature and pressure conditions for complete miscibility of silicate and hydrogen, we find that the silicate-hydrogen binary solvus will dictate the nature of atmospheres and internal layering in rocky planets that garnered H2-rich primary atmospheres. The temperatures at the surfaces of supercritical magma oceans will correspond to the silicate-hydrogen solvus. As a result, the radial positions of supercritical magma ocean–atmosphere interfaces, rather than their temperatures and pressures, should reflect the thermal states of these planets. The conditions prescribed by the solvus influence the structure of the atmosphere, and thus the transit radii of sub-Neptunes. Separation of iron-rich metal to form metal cores in sub-Neptunes and super-Earths is not assured due to prospects for neutral buoyancy of metal in silicate melt induced by dissolution of H, Si, and O in the metal at high temperatures.more » « less
-
Abstract Sub-Neptune exoplanets may have thick hydrogen envelopes and therefore develop a high-pressure interface between hydrogen and the underlying silicates/metals. Some sub-Neptunes may convert to super-Earths via massive gas loss. If hydrogen chemically reacts with oxides and metals at high pressures and temperatures (P−T), it could impact the structure and composition of the cores and atmospheres of sub-Neptunes and super-Earths. While H2gas is a strong reducing agent at low pressures, the behavior of hydrogen is unknown at theP−Texpected for sub-Neptunes’ interiors, where hydrogen is a dense supercritical fluid. Here we report experimental results of reactions between ferrous/ferric oxides and hydrogen at 20–40 GPa and 1000–4000 K utilizing the pulsed laser-heated diamond-anvil cell combined with synchrotron X-ray diffraction. Under these conditions, hydrogen spontaneously strips iron off the oxides, forming Fe-H alloys and releasing oxygen to the hydrogen medium. In a planetary context where this reaction may occur, the Fe-H alloy may sink to the metallic part of the core, while released oxygen may stabilize as water in the silicate layer, providing a mechanism to ingas hydrogen to the deep interiors of sub-Neptunes. Water produced from the redox reaction can also partition to the atmosphere of sub-Neptunes, which has important implications for understanding the composition of their atmospheres. In addition, super-Earths converted from sub-Neptunes may contain a large amount of hydrogen and water in their interiors (at least a few wt% H2O). This is distinct from smaller rocky planets, which were formed relatively dry (likely a few hundredths wt% H2O).more » « less
-
Abstract Understanding the surface temperature and interior structure of cold-to-temperate sub-Neptunes is critical for assessing their habitability, yet direct observations are challenging. In this study, we investigate the impact of water condensation on the atmospheric compositions of sub-Neptunes, focusing on the implications for James Webb Space Telescope (JWST) spectroscopic observations. By modeling the atmospheric photochemistry of two canonical sub-Neptunes, K2-18 b and LHS 1140 b, both with and without water condensation and with and without thick atmospheres, we demonstrate that water condensation can significantly affect the predicted atmospheric compositions. This effect is driven by oxygen depletion from the condensation of water vapor and primarily manifests as an increase in the C/O ratio within the photochemically active regions of the atmosphere. This change in composition particularly affects planets with thin H2-dominated atmospheres, leading to a transition in dominant nitrogen and carbon carriers from N2and oxygen-rich species like CO/CO2toward heavier hydrocarbons and nitriles. While our models do not fully account for the loss mechanisms of these higher-order species, such molecules can go on to form more refractory molecules or hazes. Planets with thin H2-rich atmospheres undergoing significant water condensation are thus likely to exhibit very hazy atmospheres. The relatively flat JWST spectra observed for LHS 1140 b could be consistent with such a scenario, suggesting a shallow surface with extensive water condensation or a high atmospheric C/O ratio. Conversely, the JWST observations of K2-18 b are better aligned with a volatile-rich mini-Neptune with a thick atmosphere.more » « less
-
Abstract Assessing the prevalence of atmospheres on rocky planets around M-dwarf stars is a top priority of exoplanet science. High-energy activity from M dwarfs can destroy the atmospheres of these planets, which could explain the lack of atmosphere detections to date. Volcanic outgassing has been proposed as a mechanism to replenish the atmospheres of tidally heated rocky planets. L 98-59 b, a sub-Earth transiting a nearby M dwarf, was recently identified as the most promising exoplanet to detect a volcanic atmosphere. We present the transmission spectrum of L 98-59 b from four transits observed with JWST NIRSpec G395H. Although the airless model provides an adequate fit to the data based on itsχ2, an SO2atmosphere is preferred by 3.6σover a flat line in terms of the Bayesian evidence. Such an atmosphere would likely be in a steady state where volcanism balances escape. If so, L 98-59 b must experience at least eight times as much volcanism and tidal heating per unit mass as Io. If volcanism is driven by runaway melting of the mantle, we predict the existence of a subsurface magma ocean in L 98-59 b extending up toRp ∼ 60%–90%. An SO2-rich volcanic atmosphere on L 98-59 b would be indicative of an oxidized mantle with an oxygen fugacity offO2 > IW + 2.7, and it would imply that L 98-59 b must have retained some of its volatile endowment despite its proximity to its star. Our findings suggest that volcanism may revive secondary atmospheres on tidally heated rocky planets around M dwarfs.more » « less
