Abstract Sub-Neptune exoplanets may have thick hydrogen envelopes and therefore develop a high-pressure interface between hydrogen and the underlying silicates/metals. Some sub-Neptunes may convert to super-Earths via massive gas loss. If hydrogen chemically reacts with oxides and metals at high pressures and temperatures (P−T), it could impact the structure and composition of the cores and atmospheres of sub-Neptunes and super-Earths. While H2gas is a strong reducing agent at low pressures, the behavior of hydrogen is unknown at theP−Texpected for sub-Neptunes’ interiors, where hydrogen is a dense supercritical fluid. Here we report experimental results of reactions between ferrous/ferric oxides and hydrogen at 20–40 GPa and 1000–4000 K utilizing the pulsed laser-heated diamond-anvil cell combined with synchrotron X-ray diffraction. Under these conditions, hydrogen spontaneously strips iron off the oxides, forming Fe-H alloys and releasing oxygen to the hydrogen medium. In a planetary context where this reaction may occur, the Fe-H alloy may sink to the metallic part of the core, while released oxygen may stabilize as water in the silicate layer, providing a mechanism to ingas hydrogen to the deep interiors of sub-Neptunes. Water produced from the redox reaction can also partition to the atmosphere of sub-Neptunes, which has important implications for understanding the composition of their atmospheres. In addition, super-Earths converted from sub-Neptunes may contain a large amount of hydrogen and water in their interiors (at least a few wt% H2O). This is distinct from smaller rocky planets, which were formed relatively dry (likely a few hundredths wt% H2O).
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This content will become publicly available on December 1, 2025
Phase Equilibria of Sub-Neptunes and Super-Earths
Abstract We investigate the consequences of nonideal chemical interaction between silicate and overlying hydrogen-rich envelopes for rocky planets using basic tenets of phase equilibria. Based on our current understanding of the temperature and pressure conditions for complete miscibility of silicate and hydrogen, we find that the silicate-hydrogen binary solvus will dictate the nature of atmospheres and internal layering in rocky planets that garnered H2-rich primary atmospheres. The temperatures at the surfaces of supercritical magma oceans will correspond to the silicate-hydrogen solvus. As a result, the radial positions of supercritical magma ocean–atmosphere interfaces, rather than their temperatures and pressures, should reflect the thermal states of these planets. The conditions prescribed by the solvus influence the structure of the atmosphere, and thus the transit radii of sub-Neptunes. Separation of iron-rich metal to form metal cores in sub-Neptunes and super-Earths is not assured due to prospects for neutral buoyancy of metal in silicate melt induced by dissolution of H, Si, and O in the metal at high temperatures.
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- Award ID(s):
- 2223935
- PAR ID:
- 10615205
- Publisher / Repository:
- American Astronomical Society
- Date Published:
- Journal Name:
- The Planetary Science Journal
- Volume:
- 5
- Issue:
- 12
- ISSN:
- 2632-3338
- Page Range / eLocation ID:
- 268
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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