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Title: Assembly and Disassembly of Supramolecular Hypervalent Iodine Macrocycles via Anion Coordination
This study explores the dynamic self-assembly and disassembly of hypervalent iodine-based macrocycles (HIMs) guided by secondary bonding interactions. The reversible disassembly and reassembly of HIMs are facilitated through anion binding via the addition of tetrabutylammonium (TBA) salts or removal of the anion by the addition of silver nitrate. The association constants for HIM monomers with TBA(Cl) and TBA(Br) are calculated and show a correlation with the strength of the iodine–anion bond. A unique tetracoordinate hypervalent iodine-based compound was identified as the disassembled monomer. Last, the study reveals the dynamic bonding nature of these macrocycles in solution, allowing for rearrangement and participation in dynamic bonding chemistry.  more » « less
Award ID(s):
2003654
PAR ID:
10553009
Author(s) / Creator(s):
; ; ; ; ; ; ;
Publisher / Repository:
American Chemical Society
Date Published:
Journal Name:
The Journal of Organic Chemistry
Volume:
89
Issue:
11
ISSN:
0022-3263
Page Range / eLocation ID:
7437 to 7445
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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