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Title: Robust superconductivity and the suppression of charge-density wave in the quasi-skutterudites Ca3(Ir1−xRhx)4Sn13 single crystals at ambient pressure
Abstract Single crystals of the quasi-skutterudite compounds Ca3(Ir1-xRhx)4Sn13(3–4–13) were synthesized by flux growth and characterized by x-ray diffraction, energy dispersive x-ray spectroscopy, magnetization, resistivity, and radio frequency magnetic susceptibility techniques. The coexistence and competition between the charge density wave (CDW) and superconductivity was studied by varying the Rh/Ir ratio. The superconducting transition temperature, T c , varies from 7 K in pure Ir (x = 0) to 8.3 K in pure Rh (x = 1). Temperature-dependent electrical resistivity reveals monotonic suppression of the CDW transition temperature,TCDW(x). The CDW starts in pure Ir,x = 0, atTCDW≈ 40 K and extrapolates roughly linearly to zero at x c 0.53–0.58 under the superconducting dome. Magnetization and transport measurements show a significant influence of CDW on superconducting and normal states. Meissner expulsion is substantially reduced in the CDW region, indicating competition between the CDW and superconductivity. The low-temperature resistivity is higher in the CDW part of the phase diagram, consistent with the reduced density of states due to CDW gapping. Its temperature dependence just above T c shows signs of non-Fermi liquid behavior in a cone-like composition pattern. We conclude that the Ca3(Ir1-xRhx)4Sn13alloy is a good candidate for a composition-driven quantum critical point at ambient pressure.  more » « less
Award ID(s):
2219901
PAR ID:
10556312
Author(s) / Creator(s):
; ; ; ; ; ;
Publisher / Repository:
Institute of Physics (IOP)
Date Published:
Journal Name:
Journal of Physics: Condensed Matter
Volume:
36
Issue:
38
ISSN:
0953-8984
Page Range / eLocation ID:
385702
Subject(s) / Keyword(s):
open access superconductivity
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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