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This paper presents a study on the characterization of density as a function of temperature for phase change materials (PCMs). More specifically, in this study we analyze organic alkane PCMs, often called paraffins. PCMs are materials that have the ability to absorb a substantial amount of heat during phase transition from solid to liquid, and therefore prove to be useful in thermal energy storage. The density of paraffin wax PCMs is largely dependent on temperature, and during the phase change process, the density decreases dramatically as the PCM transitions from solid to liquid. Consequently, the PCM experiences dramatic volumetric expansion during this transition. Besides the thermal energy storage uses of PCMs, this volumetric expansion that they exhibit is also used in thermal actuator applications, often referred to as wax motors. While density of PCMs does affect their thermal and mechanical performance, the property is not well-characterized within the literature. In this paper, we examine ten paraffin wax PCMs with varying meltingtemperatures and characterize their densities as a function of temperature. This characterization was done usinga piston and cylinder dilatometer test setup within a temperature-controlled thermal chamber that we designedand validated to the well-characterized density properties of water. The density and temperature relationships werefurther analyzed using piecewise linear regression analysis to develop mathematical models of density as it relates totemperature, which will be useful to those wishing to analyze designs in which PCMs are used, such as in PCM-filled heat sinks.
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Molecular-Level Understanding of Phase Stability in Phase-Change Nanoemulsions for Thermal Energy Storage by NMR Spectroscopy
Phase change materials (PCMs) are latent heat storage materials that can store or release thermal energy while undergoing thermodynamic phase transitions. Organic PCMs can be emulsified in water in the presence of surfactants to enhance thermal conductivity and enable applications as heat transfer fluids. However, PCM nanoemulsions often become unstable during thermal cycling. To better understand the molecular origins of phase stability in PCM nanoemulsions, we designed a model PCM nanoemulsion system and studied how the molecular-level environments and dynamics of the surfactants and oil phase changed upon thermal cycling using liquid-state nuclear magnetic resonance (NMR) spectroscopy. The model system used octadecane as the oil phase, stearic acid as the surfactant, and aqueous NaOH as the continuous phase. The liquid fraction of octadecane within the nanoemulsions was quantified noninvasively during thermal cycling by liquid-state 1H single-pulse NMR measurements, revealing the extent of octadecane supercooling as a function of temperature. The mean droplet size of the PCM nanoemulsions, measured by dynamic light scattering (DLS), was correlated with the liquid content of octadecane to explain phase instability in the solid−liquid coexistence region. Quantitative 13C single-pulse NMR experiments established that the carbonyl surfactant head groups were present in multiple distinct environments during thermal cycling. After repeated thermal cycling, the 13C signal intensity of the carbonyl surfactant head groups decreased, indicating that the surfactant head groups lost molecular mobility. The results explain, in part, the origin of phase instability of PCM nanoemulsions upon thermal cycling.
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- Award ID(s):
- 1743794
- PAR ID:
- 10562613
- Publisher / Repository:
- ACS Langmuir
- Date Published:
- Journal Name:
- Langmuir
- Volume:
- 40
- Issue:
- 41
- ISSN:
- 0743-7463
- Page Range / eLocation ID:
- 21814 to 21823
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript
- Journal Article:
- https://doi.org/10.1021/acs.langmuir.4c02997
