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Where and under what conditions the transfer of energy between electromagnetic fields and particles takes place in the solar wind remains an open question. We investigate the conditions that promote the growth of kinetic instabilities predicted by linear theory to infer how turbulence and temperature-anisotropy-driven instabilities are interrelated. Using a large dataset from Solar Orbiter, we introduce the radial rate of strain, a novel measure computed from single-spacecraft data, which we interpret as a proxy for the double-adiabatic strain rate. The solar wind exhibits high absolute values of the radial rate of strain at locations with large temperature anisotropy. We measure the kurtosis and skewness of the radial rate of strain from the statistical moments to show that it is non-Gaussian for unstable intervals and increasingly intermittent at smaller scales with a power-law scaling. We conclude that the velocity field fluctuations in the solar wind contribute to the presence of temperature anisotropy sufficient to create potentially unstable conditions.
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Local number fluctuations in ordered and disordered phases of water across temperatures: Higher-order moments and degrees of tetrahedrality
The isothermal compressibility (i.e., related to the asymptotic number variance) of equilibrium liquid water as a function of temperature is minimal under near-ambient conditions. This anomalous non-monotonic temperature dependence is due to a balance between thermal fluctuations and the formation of tetrahedral hydrogen-bond networks. Since tetrahedrality is a many-body property, it will also influence the higher-order moments of density fluctuations, including the skewness and kurtosis. To gain a more complete picture, we examine these higher-order moments that encapsulate many-body correlations using a recently developed, advanced platform for local density fluctuations. We study an extensive set of simulated phases of water across a range of temperatures (80–1600 K) with various degrees of tetrahedrality, including ice phases, equilibrium liquid water, supercritical water, and disordered nonequilibrium quenches. We find clear signatures of tetrahedrality in the higher-order moments, including the skewness and excess kurtosis, which scale for all cases with the degree of tetrahedrality. More importantly, this scaling behavior leads to non-monotonic temperature dependencies in the higher-order moments for both equilibrium and non-equilibrium phases. Specifically, under near-ambient conditions, the higher-order moments vanish most rapidly for large length scales, and the distribution quickly converges to a Gaussian in our metric. However, under non-ambient conditions, higher-order moments vanish more slowly and hence become more relevant, especially for improving information-theoretic approximations of hydrophobic solubility. The temperature non-monotonicity that we observe in the full distribution across length scales could shed light on water’s nested anomalies, i.e., reveal new links between structural, dynamic, and thermodynamic anomalies.
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- Award ID(s):
- 2133179
- PAR ID:
- 10565169
- Publisher / Repository:
- American Institute of Physics
- Date Published:
- Journal Name:
- The Journal of Chemical Physics
- Volume:
- 160
- Issue:
- 20
- ISSN:
- 0021-9606
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1063/5.0204696
