skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: From Ln 2 O 2 S to Ln 10 OS 14 : exploring the sulphur spectrum of trivalent lanthanoid oxysulphides
Lanthanoid oxysulphides exhibit great versatility in their chemical compositions which allow for their optoelectronic properties to be tuned by the relative amounts of oxygen and sulphur present in their crystal structures.  more » « less
Award ID(s):
2044403
PAR ID:
10566652
Author(s) / Creator(s):
;
Publisher / Repository:
Royal Society of Chemistry
Date Published:
Journal Name:
Dalton Transactions
Volume:
53
Issue:
16
ISSN:
1477-9226
Page Range / eLocation ID:
6855 to 6859
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract Heat capacities and enthalpies of formation of BaGd2O4were determined by high‐temperature differential scanning calorimetry and high‐temperature oxide melt solution calorimetry, respectively. Thermodynamic stability of BaLn2O4compounds increases with decreasing Ln3+ionic radius. Previously reported data on BaNd2O4and BaSm2O4corroborate this trend. Missing data for compounds in BaO–Ln2O3(Ln = La, Pr, Eu, Er) systems were estimated from established relations, thermodynamic assessment was performed, and binary phase diagrams were calculated. 
    more » « less
  2. Alcoholysis of (C5H4SiMe)3Ln results in bimetallic complexes with unexpected decreases in Ln⋯Ln distances as bridging alkoxides become bulkier. These complexes were characterized by DOSY NMR, CV, DPV, and a LaIIspecies was observed by EPR. 
    more » « less
  3. null (Ed.)