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Abstract Computational studies revealed that dirhodium tetrakis(1,2,2‐triarylcyclopropanecarboxylate) (Rh2(TPCP)4) catalysts adopt distinctive high symmetry orientations, which are dependent on the nature of the aryl substitution pattern. The parent catalyst, Rh2(TPCP)4, and those with ap‐substituent at the C1 aryl, such as Rh2(p‐BrTPCP)4and Rh2(p‐PhTPCP)4, adopt aC2‐symmetric structure. Rh2(3,5‐di(p‐tBuC6H4)TPCP)4, 3,5‐disubstituted at the C1 aryl, adopts aD2‐symmetric structure, whereas catalysts with ano‐substituent at the C1 aryl, such as Rh2(o‐Cl‐5‐BrTPCP)4,adopt aC4‐symmetric structure.
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This content will become publicly available on November 26, 2025
An unconventional charge compensation mechanism for proton insertion in aqueous Zn-ion batteries
Electrochemical cycling of the VOPO4cathode in aqueous Zn-ion batteries proceedsviaproton insertion, which is accompanied by the conformal coating of an amorphous ZnO layer on the electrode particles.
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- Award ID(s):
- 2144296
- PAR ID:
- 10568821
- Publisher / Repository:
- Royal Society of Chemistry
- Date Published:
- Journal Name:
- Journal of Materials Chemistry A
- Volume:
- 12
- Issue:
- 46
- ISSN:
- 2050-7488
- Page Range / eLocation ID:
- 31942 to 31948
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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