The noble gas isotope systematics of ocean island basalts suggest the existence of primordial mantle signatures in the deep mantle. Yet, the isotopic compositions of lithophile elements (Sr, Nd, Hf) in these lavas require derivation from a mantle source that is geochemically depleted by melt extraction rather than primitive. Here, this apparent contradiction is resolved by employing a compilation of the Sr, Nd, and Hf isotope composition of kimberlites—volcanic rocks that originate at great depth beneath continents. This compilation includes kimberlites as old as 2.06 billion years and shows that kimberlites do not derive from a primitive mantle source but sample the same geochemically depleted component (where geochemical depletion refers to ancient melt extraction) common to most oceanic island basalts, previously called PREMA (prevalent mantle) or FOZO (focal zone). Extrapolation of the Nd and Hf isotopic compositions of the kimberlite source to the age of Earth formation yields a143Nd/144Nd-176Hf/177Hf composition within error of chondrite meteorites, which include the likely parent bodies of Earth. This supports a hypothesis where the source of kimberlites and ocean island basalts contains a long-lived component that formed by melt extraction from a domain with chondritic143Nd/144Nd and176Hf/177Hf shortly after Earth accretion. The geographic distribution of kimberlites containing the PREMA component suggests that these remnants of early Earth differentiation are located in large seismically anomalous regions corresponding to thermochemical piles above the core–mantle boundary. PREMA could have been stored in these structures for most of Earth’s history, partially shielded from convective homogenization.
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Changing shape of mantle heterogeneity by melt migration beneath mid-ocean ridges
The common assumption that residual peridotites retain the Nd-Hf isotope ratios in the mantle source is debated because melt and solid of different isotopic compositions could undergo chemical exchange during melt migration, altering the isotopic signature of the source. By modeling the transport of chemical heterogeneities in the melting region beneath a mid-ocean ridge, we show that the shape of a chemical heterogeneity marked by Nd or Hf isotope ratio changes systematically through subvertical dispersion, stretching, compression, and shearing. The isotope ratios inside the chemical heterogeneity decay toward the values of background mantle. The amount of decay depends on the strength of dispersion, which itself is strongly dependent on the melt fraction in the melting region. When the maximum melt fraction is greater than 1%, buoyancy-driven melt flow relative to the solid causes subvertical dispersion of isotopic signals in the solid. Differential flows of the melt and solid also produce chromatography fractionation of Nd with respect to Hf, causing their isotope ratios to decouple. Compositions of the residue in Nd-Hf isotope ratio diagram do not record the endmembers in the source, instead they represent an area that covers part of the binary mixing line between the background mantle and the original heterogeneity. In the case of small melt fraction (<0.2%), the low permeability results in sluggish melt flow, weak dispersion, and negligible chromatography fractionation. Consequently, Nd and Hf isotope ratios in the residue remain coupled, representing the endmember isotope ratios in the source. The ridge model with larger melt fraction may correspond to the fast-spreading ridge, while the model with smaller melt fraction may correspond to the ultraslow-spreading ridge. The present study underscores the importance of melt migration processes beneath mid-ocean ridges on the deformation, mixing and decoupling of Nd-Hf isotope ratios in residual peridotites.
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- PAR ID:
- 10574490
- Publisher / Repository:
- Elsevier
- Date Published:
- Journal Name:
- Earth and Planetary Science Letters
- Edition / Version:
- 1
- Volume:
- 644
- Issue:
- C
- ISSN:
- 0012-821X
- Page Range / eLocation ID:
- 118925
- Subject(s) / Keyword(s):
- Mantle heterogeneity, Abyssal peridotite, Nd and Hf isotope ratios, Chromatography fractionation, Dispersion, Mid-ocean ridge
- Format(s):
- Medium: X Size: 4.5 Other: pdf
- Size(s):
- 4.5
- Sponsoring Org:
- National Science Foundation
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