Abstract Land use within a watershed impacts stream channel morphology and hydrology and, therefore, in‐stream solute transport processes and associated transient storage mechanisms. This study evaluated transport processes in two contrasting stream sites where channel morphology was influenced by the surrounding land use, land cover, climate and geologic controls: Como Creek, CO, a relatively undisturbed, high gradient, forested stream with a gravel bed and complex channel morphology, and Clear Creek, IA, an incised, low‐gradient stream with low‐permeability substrate draining an agricultural landscape. We performed conservative stream tracer injections at these sites to address the following questions: (1) How does solute transport vary between streams with differing morphologies? and (2) How does solute transport at each stream site change as a function of discharge? We analysed in‐stream tracer time series data and compared results quantifying solute attenuation in surface and subsurface transient storage zones. Significant trends were observed in these metrics with varying discharge conditions at the forested site but not at the agricultural site. There was a broad range of transport mechanisms and evidence of substantial exchange with both surface and hyporheic transient storage in the relatively undisturbed, forested stream. Changing discharge conditions activated or deactivated different solute transport mechanisms in the forested site and greatly impacted advective travel time. Conversely in the simplified agricultural stream, there was a narrow range of solute transport behaviour across flows and predominantly surface transient storage at all measured discharge conditions. These results demonstrate how channel simplification inhibits available solute transport mechanisms across varying discharge conditions. 
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                            Gas transfer velocity (k600) increases with discharge in steep streams but not in low‐slope streams
                        
                    
    
            Abstract Gas transfer velocity () controls gas fluxes between aquatic ecosystems and the atmosphere. In streams, is controlled by turbulence and, thus, local hydrology and geomorphology. Resultantly, variability in can be large and modeling from physical parameters can have large uncertainty. Here, we leverage a large dataset of estimates derived from tracer‐gas experiments in 22 US streams across a range of discharges. Our analysis shows that was highly variable both spatially across and temporally within streams, with estimates of spanning three orders of magnitude. Overall, scaled with discharge in steep streams due to relatively high stream power, but not in low‐slope streams, where stream power was relatively low even at high flows. Understanding how responds to stream discharge in a wide variety of streams is key to creating temporally and spatially resolved estimates of biogeochemical processes in streams. 
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                            - Award ID(s):
- 2217817
- PAR ID:
- 10577083
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Limnology and Oceanography Letters
- Volume:
- 10
- Issue:
- 3
- ISSN:
- 2378-2242
- Format(s):
- Medium: X Size: p. 308-317
- Size(s):
- p. 308-317
- Sponsoring Org:
- National Science Foundation
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