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Electrophoresis is the motion of a charged colloidal particle in an electrolyte under an applied electric field. The electrophoretic velocity of a spherical particle depends on the dimensionless electric field strength$$\beta =a^*e^*E_\infty ^*/k_B^*T^*$$, defined as the ratio of the product of the applied electric field magnitude$$E_\infty ^*$$and particle radius$$a^*$$, to the thermal voltage$$k_B^*T^*/e^*$$, where$$k_B^*$$is Boltzmann's constant,$$T^*$$is the absolute temperature, and$$e^*$$is the charge on a proton. In this paper, we develop a spectral element algorithm to compute the electrophoretic velocity of a spherical, rigid, dielectric particle, of fixed dimensionless surface charge density$$\sigma$$over a wide range of$$\beta$$. Here,$$\sigma =(e^*a^*/\epsilon ^*k_B^*T^*)\sigma ^*$$, where$$\sigma ^*$$is the dimensional surface charge density, and$$\epsilon ^*$$is the permittivity of the electrolyte. For moderately charged particles ($$\sigma ={O}(1)$$), the electrophoretic velocity is linear in$$\beta$$when$$\beta \ll 1$$, and its dependence on the ratio of the Debye length ($$1/\kappa ^*$$) to particle radius (denoted by$$\delta =1/(\kappa ^*a^*)$$) agrees with Henry's formula. As$$\beta$$increases, the nonlinear contribution to the electrophoretic velocity becomes prominent, and the onset of this behaviour is$$\delta$$-dependent. For$$\beta \gg 1$$, the electrophoretic velocity again becomes linear in field strength, approaching the Hückel limit of electrophoresis in a dielectric medium, for all$$\delta$$. For highly charged particles ($$\sigma \gg 1$$) in the thin-Debye-layer limit ($$\delta \ll 1$$), our computations are in good agreement with recent experimental and asymptotic results.
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Thin-film flow due to an asymmetric distribution of surface tension and applications to surfactant deposition
Thin-film equations are utilised in many different areas of fluid dynamics when there exists a direction in which the aspect ratio can be considered small. We consider thin free films with Marangoni effects in the extensional flow regime, where velocity gradients occur predominantly along the film. In practice, because of the local deposition of surfactants or input of energy, asymmetric distributions of surfactants or surface tension more generally, are possible. Such examples include the surface of bubbles and the rupture of thin films. In this study, we consider the asymmetric thin-film equations for extensional flow with Marangoni effects. Concentrating on the case of small Reynolds number$$ Re $$, we study the deposition of insoluble surfactants on one side of a liquid sheet otherwise at rest and the resulting thinning and rupture of the sheet. The analogous problem with a uniformly thinning liquid sheet is also considered. In addition, the centreline deformation is discussed. In particular, we show analytically that if the surface tension isotherm$$\sigma = \sigma (\varGamma )$$is nonlinear (surface tension$$\sigma$$varies with surfactant concentration$$\varGamma$$), then accounting for top–bottom asymmetry leads to slower (faster) thinning and pinching if$$\sigma = \sigma (\varGamma )$$is convex (concave). The analytical progress reported in this paper allows us to discuss the production of satellite drops from rupture via Marangoni effects, which, if relevant to surface bubbles, would be an aerosol production mechanism that is distinct from jet drops and film drops.
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- Award ID(s):
- 1844932
- PAR ID:
- 10581920
- Publisher / Repository:
- Cambridge University Press
- Date Published:
- Journal Name:
- Journal of Fluid Mechanics
- Volume:
- 992
- ISSN:
- 0022-1120
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1017/jfm.2024.501
