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Abstract An orthogonal combination of cationic and radical RAFT polymerizations is used to synthesize bottlebrush polymers using two distinct RAFT agents. Selective consumption of the first RAFT agent is used to control the cationic RAFT polymerization of a vinyl ether monomer bearing a secondary dormant RAFT agent, which subsequently allows side‐chain polymers to be grafted from the pendant RAFT agent by a radical‐mediated RAFT polymerization of a different monomer, thus completing the synthesis of bottlebrush polymers. The high efficiency and selectivity of the cationic and radical RAFT polymerizations allow both polymerizations to be conducted in one‐pot tandem without intermediate purification.
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This content will become publicly available on January 14, 2026
Mechanism and modelling of thermally initiated RAFT step-growth polymerization
Here we report the modelling of thermally initiated RAFT step-growth polymerization kinetics of maleimide and acrylate monomers with bifunctional RAFT agents bearing tertiary carboxyalkyl-stabilized fragmentable R groups.
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- Award ID(s):
- 2108670
- PAR ID:
- 10585866
- Publisher / Repository:
- RSC
- Date Published:
- Journal Name:
- Polymer Chemistry
- Volume:
- 16
- Issue:
- 3
- ISSN:
- 1759-9954
- Page Range / eLocation ID:
- 266 to 271
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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