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Abstract Enhancing reactive species transport at the plasma–liquid interface is important for scaling of atmospheric pressure plasmas studied in the laboratory to real-world applications. It is well-known that the introduction of turbulence at any interface will enhance mixing by enhancing species uptake from the gas phase to the liquid phase by surface renewal processes, entrainment, bubbles and surface area modification. The goal of this work is to isolate surface effects associated with turbulence from the multitude of turbulent transport enhanced processes by artificially introducing surface perturbations using Faraday waves. Experiments were conducted to determine decoloration rate constants of a model contaminant (methylene blue) as a function of both discharge features (including positive and negative streamers) and hydrodynamics (Faraday surface wavelengths). The local plasma ionization wave at the interfacial structure was modeled and compared to experiments. Interestingly, it was found in experiments that plasma in contact with the water also generated capillary waves thus modifying the surface as well. Plasma ionization waves in combination with acoustic driven Faraday waves adds to the complexity of interpreting the effects of, for example, surface area increases, due to these complex coupled phenomenon. Local plasma ionization wave structure appears to be modified (increased propagation distance) when the liquid is perturbed, leading to increased contact of the liquid water surface with reactive species. Along with interfacial surface area growth, nonlinear convective transport is also increased with perturbations, leading to the general realization that acoustic perturbations can improve transport and thus decoloration of the model contaminant dye.
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Noncapillary Wave Dynamics due to Interfacial Coupling with Plasma Patterns at a Liquid Surface
We identify a new class of surface waves that arise at a plasma-liquid interface due to resonant coupling between discrete plasma pattern modes and a continuum of interfacial liquid surface wave modes. A wave mode is selected due to localized excitation by the plasma, and standing waves result when waves excited from different locations interact. These waves propagate with a slower phase velocity than traditional capillary waves, but exhibit the same damping behavior with respect to liquid viscosity. Surface tension does not appear to play a significant role. We propose a curvature-dependent Maxwell pressure mechanism to explain these nondispersive interfacial waves in the presence of plasma.
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- Award ID(s):
- 2206420
- PAR ID:
- 10586047
- Publisher / Repository:
- American Physics Society Physical Review Journals
- Date Published:
- Journal Name:
- Physical Review Letters
- Volume:
- 133
- Issue:
- 10
- ISSN:
- 0031-9007
- Page Range / eLocation ID:
- 105301
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript
- Journal Article:
- https://doi.org/10.1103/PhysRevLett.133.105301
