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This content will become publicly available on March 13, 2026

Title: Ro-vibrational dynamics of the neon dimer
Abstract Short intense laser pulses are routinely used to induce rotational wave packet dynamics of molecules. Ro-vibrational wave packet dynamics has been explored comparatively infrequently, focusing predominantly on extremely light and rigid molecules such as H 2 + , H2and D2. This work presents quantum mechanical calculations that account for the rotationalandthe vibrational degrees of freedom for a heavier and rather floppy diatomic molecule, namely the neon dimer. For pumping by a strong and short non-resonant pump pulse, we identify several phenomena that depend critically on the vibrational (i.e. radial) degree of freedom. Our calculations show (i) fingerprints of the radial dynamics in the alignment signal; (ii) laser-kick induced dissociative dynamics on very short time scales (ejection of highly structured ‘jets’); and (iii) tunneling dynamics that signifies the existence of resonance states, which are supported by the effective potential curves for selected finite relative angular momenta. Our theory predictions can be explored by existing state-of-the-art experiments.  more » « less
Award ID(s):
2409311 2110158 2409600
PAR ID:
10587432
Author(s) / Creator(s):
; ; ; ;
Publisher / Repository:
IOP
Date Published:
Journal Name:
Journal of Physics B: Atomic, Molecular and Optical Physics
Volume:
58
Issue:
6
ISSN:
0953-4075
Page Range / eLocation ID:
065601
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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