Abstract Letk(B0) andl(B0) respectively denote the number of ordinary andp-Brauer irreducible characters in the principal blockB0of a finite groupG. We prove that, ifk(B0)−l(B0) = 1, thenl(B0) ≥p− 1 or elsep= 11 andl(B0) = 9. This follows from a more general result that for every finite groupGin which all non-trivialp-elements are conjugate,l(B0) ≥p− 1 or elsep= 11 and$$G/{{\bf{O}}_{{p^\prime }}}(G) \cong C_{11}^2\, \rtimes\,{\rm{SL}}(2,5)$$ . These results are useful in the study of principal blocks with few characters. We propose that, in every finite groupGof order divisible byp, the number of irreducible Brauer characters in the principalp-block ofGis always at least$$2\sqrt {p - 1} + 1 - {k_p}(G)$$ , wherekp(G) is the number of conjugacy classes ofp-elements ofG. This indeed is a consequence of the celebrated Alperin weight conjecture and known results on bounding the number ofp-regular classes in finite groups.
more »
« less
From cubane-assembled Mn-oxo clusters to monodispersed manganese oxide colloidal nanocrystals
The high nuclearity cubane-assembled Mn-oxo clusters serve as effective precursors for the preparation of monodispersed Mn3O4nanocrystals through the colloidal chemistry approach.
more »
« less
- Award ID(s):
- 1955585
- PAR ID:
- 10590351
- Publisher / Repository:
- RSC
- Date Published:
- Journal Name:
- Chemical Science
- Volume:
- 15
- Issue:
- 27
- ISSN:
- 2041-6520
- Page Range / eLocation ID:
- 10381 to 10391
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Abstract We present the spectroscopic characterization of cyclopropenethione in the laboratory and detect it in space using the Green Bank Telescope Observations of TMC-1: Hunting Aromatic Molecules survey. The detection of this molecule—the missing link in understanding the C3H2S isomeric family in TMC-1—completes the detection of all three low-energy isomers of C3H2S, as both CH2CCS and HCCCHS have been previously detected in this source. The total column density of this molecule (NTof cm−2at an excitation temperature of K) is smaller than both CH2CCS and HCCCHS and follows nicely the relative dipole principle (RDP), a kinetic rule of thumb for predicting isomer abundances that suggests that, all other chemistry among a family of isomers being the same, the member with the smallest dipole (μ) should be the most abundant. The RDP now holds for the astronomical abundance ratios of both the S-bearing and O-bearing counterparts observed in TMC-1; however, CH2CCO continues to elude detection in any astronomical source.more » « less
-
Abstract The cluster mass–richness relation (MRR) is an observationally efficient and potentially powerful cosmological tool for constraining the matter density Ωmand the amplitude of fluctuationsσ8using the cluster abundance technique. We derive the MRR relation usingGalWCat19, a publicly available galaxy cluster catalog we created from the Sloan Digital Sky Survey-DR13 spectroscopic data set. In the MRR, cluster mass scales with richness as . We find that the MRR we derive is consistent with both the IllustrisTNG and mini-Uchuu cosmological numerical simulations, with a slope ofβ≈ 1. We use the MRR we derived to estimate cluster masses from theGalWCat19catalog, which we then use to set constraints on Ωmandσ8. Utilizing the all-member MRR, we obtain constraints of Ωm= andσ8= , and utilizing the red member MRR only, we obtain Ωm= andσ8= . Our constraints on Ωmandσ8are consistent and very competitive with the Planck 2018 results.more » « less
-
Abstract Single crystals of disordered Mn4–xCrxAl11have been synthesized via the flux method. EDS on several crystals of various sizes and shapes revealed an average molar ratio of 17:9:74 for Mn:Cr:Al, while X-ray diffraction on three different crystals yield compositions Mn2.26Cr1.74Al11(Mn4–xCrxAl11,x= 1.74), Mn0.83Cr3.17Al11, and Mn1.07Cr2.93Al11. This compound crystallizes in space groupP–1, isostructural with both Mn4Al11and Cr4Al11. Magnetic measurements on several crystals show that this disordered compound is ferrimagnetic with a low effective moment ofμeff≈1.012±0.004 μB/f.u. and a non-reachable transition temperature. DFT calculations display opening of a bandgap in the spin-up channel near the Fermi level with increasing Cr content, an indication of half-metallicity.more » « less
-
Abstract Stellar positions and velocities from Gaia are yielding a new view of open cluster dispersal. Here we present an analysis of a group of stars spanning Cepheus (l= 100°) to Hercules (l= 40°), hereafter the Cep-Her complex. The group includes four Kepler objects of interest: Kepler-1643 b (Rp= 2.32 ± 0.13R⊕,P= 5.3 days), KOI-7368 b (Rp= 2.22 ± 0.12R⊕,P= 6.8 days), KOI-7913 Ab (Rp= 2.34 ± 0.18R⊕,P= 24.2 days), and Kepler-1627 Ab (Rp= 3.85 ± 0.11R⊕,P= 7.2 days). The latter Neptune-sized planet is in part of the Cep-Her complex called theδLyr cluster. Here we focus on the former three systems, which are in other regions of the association. Based on kinematic evidence from Gaia, stellar rotation periods from TESS, and spectroscopy, these three objects are also ≈40 million years (Myr) old. More specifically, we find that Kepler-1643 is Myr old, based on its membership in a dense subcluster of the complex called RSG-5. KOI-7368 and KOI-7913 are Myr old, and are in a diffuse region that we call CH-2. Based on the transit shapes and high-resolution imaging, all three objects are most likely planets, with false-positive probabilities of 6 × 10−9, 4 × 10−3, and 1 × 10−4for Kepler-1643, KOI-7368, and KOI-7913, respectively. These planets demonstrate that mini-Neptunes with sizes of ≈2 Earth radii exist at ages of 40 Myr.more » « less
An official website of the United States government

