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Abstract Organic and inorganic stable isotopes of lacustrine carbonate sediments are commonly used in reconstructions of ancient terrestrial ecosystems and environments. Microbial activity and local hydrological inputs can alter porewater chemistry (e.g., pH, alkalinity) and isotopic composition (e.g., δ18Owater, δ13CDIC), which in turn has the potential to impact the stable isotopic compositions recorded and preserved in lithified carbonate. The fingerprint these syngenetic processes have on lacustrine carbonate facies is yet unknown, however, and thus, reconstructions based on stable isotopes may misinterpret diagenetic records as broader climate signals. Here, we characterize geochemical and stable isotopic variability of carbonate minerals, organic matter, and water within one modern lake that has known microbial influences (e.g., microbial mats and microbialite carbonate) and combine these data with the context provided by 16S rRNA amplicon sequencing community profiles. Specifically, we measure oxygen, carbon, and clumped isotopic compositions of carbonate sediments (δ18Ocarb, δ13Ccarb, ∆47), as well as carbon isotopic compositions of bulk organic matter (δ13Corg) and dissolved inorganic carbon (DIC; δ13CDIC) of lake and porewater in Great Salt Lake, Utah from five sites and three seasons. We find that facies equivalent to ooid grainstones provide time‐averaged records of lake chemistry that reflect minimal alteration by microbial activity, whereas microbialite, intraclasts, and carbonate mud show greater alteration by local microbial influence and hydrology. Further, we find at least one occurrence of ∆47isotopic disequilibrium likely driven by local microbial metabolism during authigenic carbonate precipitation. The remainder of the carbonate materials (primarily ooids, grain coatings, mud, and intraclasts) yield clumped isotope temperatures (T(∆47)), δ18Ocarb, and calculated δ18Owaterin isotopic equilibrium with ambient water and temperature at the time and site of carbonate precipitation. Our findings suggest that it is possible and necessary to leverage diverse carbonate facies across one sedimentary horizon to reconstruct regional hydroclimate and evaporation–precipitation balance, as well as identify microbially mediated carbonate formation.
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This content will become publicly available on May 1, 2026
The Hydroclimate and Environmental Response to Middle Miocene Warming in the Southwestern USA: Stable Isotope Evidence
Abstract Predictions for the southwestern US with warming often suggest increased aridity. We investigate the sedimentary record of the Miocene Climate Optimum and Transition (MCO and MCT; ∼17–14 Ma) in northern New Mexico to understand the impact of warmer global temperatures and higherpCO2on southwestern US hydroclimate. The MCO and MCT comprised a globally warmer period with elevatedpCO2similar to end‐of‐the‐century (∼400–800 ppm) projections. We present new stable isotope (δ18O and δ13C) records of vadose‐zone and groundwater terrestrial carbonates and of modern precipitation, stream, and groundwater from the Española basin in northern New Mexico and establish a high‐resolution age model using new40Ar/39Ar ages. We interpret δ18O as reflecting the balance between summertime monsoonal and wintertime precipitation and δ13C as a reflection of plant productivity. Terrestrial carbonate δ18O is lowest during the MCO and MCT and is correlated with terrestrial carbonate δ13C and anti‐correlated with the benthic δ18O record. We interpret these data as recording an overall winter‐wet climate during the MCO and MCT, but that precipitation seasonality varied in response to changes in global climate during this period. The further correlation with carbonate δ13C suggests that plant productivity was driven by the amount of wintertime precipitation. Comparison with middle Miocene climate model simulations reveals that higher CO2drives a shift toward wintertime precipitation. Though paleogeographic changes may obscure a direct comparison to modern warming, overall, our findings suggest that prolonged global warmth may be associated with increased wintertime precipitation and greater primary productivity in northern New Mexico.
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- Award ID(s):
- 2202916
- PAR ID:
- 10592170
- Publisher / Repository:
- Wiley
- Date Published:
- Journal Name:
- Paleoceanography and Paleoclimatology
- Volume:
- 40
- Issue:
- 5
- ISSN:
- 2572-4517
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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