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Abstract Lacustrine carbonates are a powerful archive of paleoenvironmental information but are susceptible to post‐depositional alteration. Microbial metabolisms can drive such alteration by changing carbonate saturationin situ, thereby driving dissolution or precipitation. The net impact these microbial processes have on the primary δ18O, δ13C, and Δ47values of lacustrine carbonate is not fully known. We studied the evolution of microbial community structure and the porewater and sediment geochemistry in the upper ~30 cm of sediment from two shoreline sites at Green Lake, Fayetteville, NY over 2 years of seasonal sampling. We linked seasonal and depth‐based changes of porewater carbonate chemistry to microbial community composition, in situ carbon cycling (using δ13C values of carbonate, dissolved inorganic carbon (DIC), and organic matter), and dominant allochems and facies. We interpret that microbial processes are a dominant control on carbon cycling within the sediment, affecting porewater DIC, aqueous carbon chemistry, and carbonate carbon and clumped isotope geochemistry. Across all seasons and sites, microbial organic matter remineralization lowers the δ13C of the porewater DIC. Elevated carbonate saturation states in the sediment porewaters (Ω > 3) were attributed to microbes from groups capable of sulfate reduction, which were abundant in the sediment below 5 cm depth. The nearshore carbonate sediments at Green Lake are mainly composed of microbialite intraclasts/oncoids, charophytes, larger calcite crystals, and authigenic micrite—each with a different origin. Authigenic micrite is interpreted to have precipitated in situ from the supersaturated porewaters from microbial metabolism. The stable carbon isotope values (δ13Ccarb) and clumped isotope values (Δ47) of bulk carbonate sediments from the same depth horizons and site varied depending on both the sampling season and the specific location within a site, indicating localized (μm to mm) controls on carbon and clumped isotope values. Our results suggest that biological processes are a dominant control on carbon chemistry within the sedimentary subsurface of the shorelines of Green Lake, from actively forming microbialites to pore space organic matter remineralization and micrite authigenesis. A combination of biological activity, hydrologic balance, and allochem composition of the sediments set the stable carbon, oxygen, and clumped isotope signals preserved by the Green Lake carbonate sediments.
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How Hot Is Too Hot? Disentangling Mid‐Cretaceous Hothouse Paleoclimate From Diagenesis
Abstract The North American Newark Canyon Formation (NCF; ∼113–98 Ma) presents an opportunity to examine how terrestrial carbonate facies reflect different aspects of paleoclimate during one of the hottest periods of Earth's history. The lower NCF type section preserves heterogeneous palustrine facies and the upper NCF preserves lacustrine deposits. We combined carbonate facies analysis withδ13C,δ18O, and Δ47data sets to assess which carbonate facies preserve stable isotope signals that are most representative of climatic conditions. Palustrine facies record the heterogeneity of the original wetland environment in which they formed. Using the pelmicrite facies that formed in deeper wetlands, we interpret a lower temperature zone (35–40°C) to reflect warm season water temperatures. In contrast, a mottled micrite facies which formed in shallower wetlands records hotter temperatures (36–68°C). These hotter temperatures reflect radiatively heated “bare‐skin” temperatures that occurred in a shallow depositional setting. The lower lacustrine unit has been secondarily altered by hydrothermal fluids while the upper lacustrine unit likely preserves primary temperatures andδ18Owaterof catchment‐integrated precipitation. Resultantly, the palustrine pelmicrite and lacustrine micrite are the facies most likely to reflect ambient climate conditions, and therefore, are the best facies to use for paleoclimate interpretations. Average warm season water temperatures of 41.1 ± 3.6°C and 37.8 ± 2.5°C are preserved by the palustrine pelmicrite (∼113–112 Ma) and lacustrine micrite (∼112–103 Ma), respectively. These data support previous interpretations of the mid‐Cretaceous as a hothouse climate and demonstrate the importance of characterizing facies for identifying the data most representative of past climates.
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- Award ID(s):
- 1524785
- PAR ID:
- 10382529
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Paleoceanography and Paleoclimatology
- Volume:
- 37
- Issue:
- 12
- ISSN:
- 2572-4517
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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