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Title: Guest removal from ring-banded guanidinium organosulfonate hydrogen-bonded frameworks
Crystalline fibers of the hydrogen-bonded framework bis(guanidinium) naphthalene-1,5-disulfonate, (G)2(1,5-NDS), with ethanol guest molecules twist as they grow when deposited from solution under conditions that favor low nucleation densities and high branching rates. Spherulites comprising helicoidal fibers with a pitch of 3.4 ± 0.5 μm display rhythmic concentric variations in interference colors between crossed polarizers. Tightly packed fibers and platelets, systematically change orientations between flat-on and edge-on crystallites with respect to the substrate surface. Mueller matrix imaging reveals periodic oscillations in the absolute magnitude of the linear retardance and an associated bisignate circular retardance. Single-crystal X-ray diffraction data demonstrates that the twisted (G)2(1,5-NDS)⊃EtOH crystals adopt a bilayer packing motif with ethanol as guest molecules (space group P1 ̅). When the banded spherulite films were subsequently heated at 130°C, the solvated phase was converted to a guest-free crystalline phase (space group P21/c). This transition resulted in loss of linear retardance.  more » « less
Award ID(s):
2002964
PAR ID:
10595319
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ;
Publisher / Repository:
The Royal Society of Chemistry
Date Published:
Journal Name:
Nanoscale
ISSN:
2040-3364
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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