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Abstract Control over the copy number and nanoscale positioning of quantum dots (QDs) is critical to their application to functional nanomaterials design. However, the multiple non-specific binding sites intrinsic to the surface of QDs have prevented their fabrication into multi-QD assemblies with programmed spatial positions. To overcome this challenge, we developed a general synthetic framework to selectively attach spatially addressable QDs on 3D wireframe DNA origami scaffolds using interfacial control of the QD surface. Using optical spectroscopy and molecular dynamics simulation, we investigated the fabrication of monovalent QDs of different sizes using chimeric single-stranded DNA to control QD surface chemistry. By understanding the relationship between chimeric single-stranded DNA length and QD size, we integrated single QDs into wireframe DNA origami objects and visualized the resulting QD-DNA assemblies using electron microscopy. Using these advances, we demonstrated the ability to program arbitrary 3D spatial relationships between QDs and dyes on DNA origami objects by fabricating energy-transfer circuits and colloidal molecules. Our design and fabrication approach enables the geometric control and spatial addressing of QDs together with the integration of other materials including dyes to fabricate hybrid materials for functional nanoscale photonic devices.
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This content will become publicly available on April 14, 2026
Silicon quantum dot-molecule hybrid systems and their applications
Si quantum dot (QD)-molecule hybrid systems have emerged as a popular architecture in many research fields due to the ability to select for the advantages conferred by the inorganic Si component and the organic sections. This perspective will focus on the optical properties of Si QDs, the parameters that affect Si QD photophysics or energy transfer in Si QD-molecule hybrid structures, and their resultant hybrid optoelectronic devices. Examples of recent applications that employ Si QD-molecule hybrid materials are presented. Finally, we discuss current issues involving basic structure–property relationships that need to be addressed for Si QDs and conclude with an outlook on the bright future of Si QD-molecule hybrid materials.
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- PAR ID:
- 10596810
- Publisher / Repository:
- AIP
- Date Published:
- Journal Name:
- The Journal of Chemical Physics
- Volume:
- 162
- Issue:
- 14
- ISSN:
- 0021-9606
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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