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Abstract Herein we report on the development of an oxidative allylic C−H etherification reaction, utilizing internal olefins and alcohols as simple precursors. Key advances include the use of RhCp* complexes to promote the allylic C−H functionalization of internal olefins and the compatibility of the oxidative conditions with oxidatively sensitive alcohols, enabling the direct etherification reaction. Preliminary mechanistic studies, consistent with C−H functionalization as the rate determining step, are presented.
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This content will become publicly available on December 18, 2025
Intermolecular interaction potential maps from energy decomposition for interpreting reactivity and intermolecular interactions
The development and application of intermolecular interaction potential maps to rationalize a range of interactions at the DFT level using suitable probes is described.
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- Award ID(s):
- 2305006
- PAR ID:
- 10613841
- Publisher / Repository:
- Royal Society of Chemistry
- Date Published:
- Journal Name:
- Physical Chemistry Chemical Physics
- Volume:
- 27
- Issue:
- 1
- ISSN:
- 1463-9076
- Page Range / eLocation ID:
- 47 to 61
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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