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1. The Metallicity and Carbon-to-oxygen Ratio of the Ultrahot Jupiter WASP-76b from Gemini-S/IGRINS

   https://doi.org/10.3847/1538-3881/ad4a5f  

   Weiner_Mansfield, Megan; Line, Michael R; Wardenier, Joost P; Brogi, Matteo; Bean, Jacob L; Beltz, Hayley; Smith, Peter; Zalesky, Joseph A; Batalha, Natasha; Kempton, Eliza M-R; et al (June 2024, The Astronomical Journal)

   Abstract Measurements of the carbon-to-oxygen (C/O) ratios of exoplanet atmospheres can reveal details about their formation and evolution. Recently, high-resolution cross-correlation analysis has emerged as a method of precisely constraining the C/O ratios of hot Jupiter atmospheres. We present two transits of the ultrahot Jupiter WASP-76b observed between 1.4 and 2.4μm with the high-resolution Immersion GRating INfrared Spectrometer on the Gemini-S telescope. We detected the presence of H₂O, CO, and OH at signal-to-noise ratios of 6.93, 6.47, and 3.90, respectively. We performed two retrievals on this data set. A free retrieval for abundances of these three species retrieved a volatile metallicity of $\left(\frac{\mathrm{C}+\mathrm{O}}{\mathrm{H}}\right)=-{0.70}_{-0.93}^{+1.27}$, consistent with the stellar value, and a supersolar carbon-to-oxygen ratio of C/O $={0.80}_{-0.11}^{+0.07}$. We also ran a chemically self-consistent grid retrieval, which agreed with the free retrieval within 1σbut favored a slightly more substellar metallicity and solar C/O ratio ( $\left(\frac{\mathrm{C}+\mathrm{O}}{\mathrm{H}}\right)=-{0.74}_{-0.17}^{+0.23}$and C/O $={0.59}_{-0.14}^{+0.13}$). A variety of formation pathways may explain the composition of WASP-76b. Additionally, we found systemic (V_sys) and Keplerian (K_p) velocity offsets which were broadly consistent with expectations from 3D general circulation models of WASP-76b, with the exception of a redshiftedV_sysfor H₂O. Future observations to measure the phase-dependent velocity offsets and limb differences at high resolution on WASP-76b will be necessary to understand the H₂O velocity shift. Finally, we find that the population of exoplanets with precisely constrained C/O ratios generally trends toward super-solar C/O ratios. More results from high-resolution observations or JWST will serve to further elucidate any population-level trends. 

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2. Keck Planet Imager and Characterizer Emission Spectroscopy of WASP-33b

   https://doi.org/10.3847/1538-3881/acda91  

   Finnerty, Luke; Schofield, Tobias; Sappey, Ben; Xuan, Jerry W.; Ruffio, Jean-Baptiste; Wang, Jason J.; Delorme, Jacques-Robert; Blake, Geoffrey A.; Buzard, Cam; Fitzgerald, Michael P.; et al (June 2023, The Astronomical Journal)

   Abstract We present Keck Planet Imager and Characterizer (KPIC) high-resolution (R∼35,000)K-band thermal emission spectroscopy of the ultrahot Jupiter WASP-33b. The use of KPIC’s single-mode fibers greatly improves both blaze and line-spread stabilities relative to slit spectrographs, enhancing the cross-correlation detection strength. We retrieve the dayside emission spectrum with a nested-sampling pipeline, which fits for orbital parameters, the atmospheric pressure–temperature profile, and the molecular abundances. We strongly detect the thermally inverted dayside and measure mass-mixing ratios for CO ( ${\mathrm{logCO}}_{\mathrm{MMR}}=-{1.1}_{-0.6}^{+0.4}$), H₂O ( ${\mathrm{logH}}_2{\mathrm{O}}_{\mathrm{MMR}}=-{4.1}_{-0.9}^{+0.7}$), and OH ( ${\mathrm{logOH}}_{\mathrm{MMR}}=-{2.1}_{-1.1}^{+0.5}$), suggesting near-complete dayside photodissociation of H₂O. The retrieved abundances suggest a carbon- and possibly metal-enriched atmosphere, with a gas-phase C/O ratio of ${0.8}_{-0.2}^{+0.1}$, consistent with the accretion of high-metallicity gas near the CO₂snow line and post-disk migration or with accretion between the soot and H₂O snow lines. We also find tentative evidence for¹²CO/¹³CO ∼ 50, consistent with values expected in protoplanetary disks, as well as tentative evidence for a metal-enriched atmosphere (2–15 × solar). These observations demonstrate KPIC’s ability to characterize close-in planets and the utility of KPIC’s improved instrumental stability for cross-correlation techniques. 

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3. IGRINS Observations of WASP-127 b: H ₂ O, CO, and Super-solar Atmospheric Metallicity in the Inflated Sub-Saturn

   https://doi.org/10.3847/1538-3881/ad72f3  

   Kanumalla, Krishna; Line, Michael R; Weiner_Mansfield, Megan; Welbanks, Luis; Smith, Peter_C B; Bean, Jacob L; Pino, Lorenzo; Brogi, Matteo; Panwar, Vatsal (October 2024, The Astronomical Journal)

   Abstract High-resolution spectroscopy of exoplanet atmospheres provides insights into their composition and dynamics from the resolved line shape and depth of thousands of spectral lines. WASP-127 b is an extremely inflated sub-Saturn (R_p= 1.311R_Jup,M_p= 0.16M_Jup) with previously reported detections of H₂O and CO₂. However, the seeming absence of the primary carbon reservoir expected at WASP-127 b temperatures (T_eq∼1400 K) from chemical equilibrium, CO, posed a mystery. In this manuscript, we present the analysis of high-resolution observations of WASP-127 b with the Immersion Grating Infrared Spectrometer on Gemini South. We confirm the presence of H₂O (8.67σ) and report the detection of CO (4.34σ). Additionally, we conduct a suite of Bayesian retrieval analyses covering a hierarchy of model complexity and self-consistency. When freely fitting for the molecular gas volume mixing ratios, we obtain super-solar metal enrichment for H₂O abundance of log₁₀X ${}_{{\mathrm{H}}_2\mathrm{O}}$= −1.23 ${}_{-0.49}^{+0.29}$and a lower limit on the CO abundance of log₁₀X_CO≥–2.20 at 2σconfidence. We also report tentative evidence of photochemistry in WASP-127 b based upon the indicative depletion of H₂S. This is also supported by the data preferring models with photochemistry over free-chemistry and thermochemistry. The overall analysis implies a super-solar (∼39× Solar; [M/H] = ${1.59}_{-0.30}^{+0.30}$) metallicity for the atmosphere of WASP-127 b and an upper limit on its atmospheric C/O ratio as < 0.68. 

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4. Retrieving C and O Abundance of HR 8799 c by Combining High- and Low-resolution Data

   https://doi.org/10.3847/1538-3881/ac9f19  

   Wang 王, Ji 吉.; Wang 王, Jason J. 劲飞; Ruffio, Jean-Baptiste; Blake, Geoffrey A.; Mawet, Dimitri; Baker, Ashley; Bartos, Randall; Bond, Charlotte Z.; Calvin, Benjamin; Cetre, Sylvain; et al (December 2022, The Astronomical Journal)

   Abstract The formation and evolution pathway for the directly imaged multiplanetary system HR 8799 remains mysterious. Accurate constraints on the chemical composition of the planetary atmosphere(s) are key to solving the mystery. We perform a detailed atmospheric retrieval on HR 8799 c to infer the chemical abundances and abundance ratios using a combination of photometric data along with low- and high-resolution spectroscopic data (R∼ 20–35,000). We specifically retrieve [C/H], [O/H], and C/O and find them to be ${0.55}_{-0.39}^{+0.36}$, ${0.47}_{-0.32}^{+0.31}$, and ${0.67}_{-0.15}^{+0.12}$at 68% confidence. The superstellar C and O abundances, yet a stellar C/O ratio, reveal a potential formation pathway for HR 8799 c. Planet c, and likely the other gas giant planets in the system, formed early on (likely within ∼1 Myr), followed by further atmospheric enrichment in C and O through the accretion of solids beyond the CO ice line. The enrichment either preceded or took place during the early phase of the inward migration to the current planet locations. 

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5. Atmospheric Metallicity and C/O of HD 189733 b from High-resolution Spectroscopy

   https://doi.org/10.3847/1538-3881/ad1180  

   Finnerty, Luke; Xuan, Jerry W.; Xin, Yinzi; Liberman, Joshua; Schofield, Tobias; Fitzgerald, Michael P.; Agrawal, Shubh; Baker, Ashley; Bartos, Randall; Blake, Geoffrey A.; et al (January 2024, The Astronomical Journal)

   Abstract We present high-resolutionK-band emission spectra of the quintessential hot Jupiter HD 189733 b from the Keck Planet Imager and Characterizer. Using a Bayesian retrieval framework, we fit the dayside pressure–temperature profile, orbital kinematics, mass-mixing ratios of H₂O, CO, CH₄, NH₃, HCN, and H₂S, and the¹³CO/¹²CO ratio. We measure mass fractions of ${\mathrm{logH}}_2\mathrm{O}=-{2.0}_{-0.4}^{+0.4}$and $\mathrm{logCO}=-{2.2}_{-0.5}^{+0.5}$, and place upper limits on the remaining species. Notably, we find logCH₄< −4.5 at 99% confidence, despite its anticipated presence at the equilibrium temperature of HD 189733 b assuming local thermal equilibrium. We make a tentative (∼3σ) detection of¹³CO, and the retrieved posteriors suggest a¹²C/¹³C ratio similar to or substantially less than the local interstellar value. The possible¹³C enrichment would be consistent with accretion of fractionated material in ices or in the protoplanetary disk midplane. The retrieved abundances correspond to a substantially substellar atmospheric C/O = 0.3 ± 0.1, while the carbon and oxygen abundances are stellar to slightly superstellar, consistent with core-accretion models which predict an inverse correlation between C/O and metallicity. The specific combination of low C/O and high metallicity suggests significant accretion of solid material may have occurred late in the formation process of HD 189733 b. 

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