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1. Metal–ligand cooperativity enables zero-valent metal transfer

   https://doi.org/10.1039/D4SC07938H  

   Riu, Martin-Louis Y; Shan, Jing-Ran; Houk, K N; Nava, Matthew (February 2025, Chemical Science)

   Group 13 aminoxy complexes, (L)E(TEMPO)₃(TEMPO = 2,2,6,6-tetramethylpiperidine 1-oxyl; L = THF (tetrahydrofuran) or Py (pyridine); E = Al, Ga, In), display ambiphilic reactivity with H₂and function as synthons for the preparation of materials. 

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2. Metal-Mediated Ligand Affinity Chemistry (MLAC)

   https://doi.org/10.1007/978-1-0716-3469-1_6  

   Gukathasan, Sailajah; Awuah, Samuel G (September 2023, Springer US)
3. Quantifying the Interdependence of Metal–Ligand Covalency and Bond Distance Using Ligand K‐edge XAS

   https://doi.org/10.1002/anie.201905635  

   Lee, Kyounghoon; Blake, Anastasia V.; Donahue, Courtney M.; Spielvogel, Kyle D.; Bellott, Brian J.; Daly, Scott R. (August 2019, Angewandte Chemie International Edition)

   Abstract Bond distance is a common structural metric used to assess changes in metal–ligand bonds, but it is not clear how sensitive changes in bond distances are with respect to changes in metal–ligand covalency. Here we report ligand K‐edge XAS studies on Ni and Pd complexes containing different phosphorus(III) ligands. Despite the large number of electronic and structural permutations, P K‐edge pre‐edge peak intensities reveal a remarkable correlation that spectroscopically quantifies the linear interdependence of covalent M−P σ bonding and bond distance. Cl K‐edge studies conducted on many of the same Ni and Pd compounds revealed a poor correlation between M−Cl bond distance and covalency, but a strong correlation was established by analyzing Cl K‐edge data for Ti complexes with a wider range of Ti−Cl bond distances. Together these results establish a quantitative framework to begin making more accurate assessments of metal–ligand covalency using bond distances from readily‐available crystallographic data. 

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4. Thermodynamic stability of ligand-protected metal nanoclusters

   https://doi.org/10.1038/ncomms15988  

   Taylor, Michael G.; Mpourmpakis, Giannis (July 2017, Nature Communications)
5. Computational chemistry considerations in catalysis: Regioselectivity and metal-ligand dissociation

   https://doi.org/10.1016/j.cattod.2020.07.057  

   Patel, Prajay; Wilson, Angela K. (December 2020, Catalysis Today)

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