Abstract We define a type of modulus$$\operatorname {dMod}_p$$ for Lipschitz surfaces based on$$L^p$$ -integrable measurable differential forms, generalizing the vector modulus of Aikawa and Ohtsuka. We show that this modulus satisfies a homological duality theorem, where for Hölder conjugate exponents$$p, q \in (1, \infty )$$ , every relative Lipschitzk-homology classchas a unique dual Lipschitz$$(n-k)$$ -homology class$$c'$$ such that$$\operatorname {dMod}_p^{1/p}(c) \operatorname {dMod}_q^{1/q}(c') = 1$$ and the Poincaré dual ofcmaps$$c'$$ to 1. As$$\operatorname {dMod}_p$$ is larger than the classical surface modulus$$\operatorname {Mod}_p$$ , we immediately recover a more general version of the estimate$$\operatorname {Mod}_p^{1/p}(c) \operatorname {Mod}_q^{1/q}(c') \le 1$$ , which appears in works by Freedman and He and by Lohvansuu. Our theory is formulated in the general setting of Lipschitz Riemannian manifolds, though our results appear new in the smooth setting as well. We also provide a characterization of closed and exact Sobolev forms on Lipschitz manifolds based on integration over Lipschitzk-chains.
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Quantifying effects of second-sphere cationic groups on redox properties of dimolybdenum quadruple bonds
Placing cationic groups in the secondary coordination sphere of dimolybdenum paddlewheel complexes has allowed for quantification of electrostatic field effects on the MoMo quadruple bond.
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- Award ID(s):
- 2350403
- PAR ID:
- 10626435
- Publisher / Repository:
- Royal Society of Chemistry
- Date Published:
- Journal Name:
- Chemical Communications
- Volume:
- 60
- Issue:
- 73
- ISSN:
- 1359-7345
- Page Range / eLocation ID:
- 9966 to 9969
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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