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Abstract From transmission electron microscopy and other laboratory studies of presolar grains, the implicit condensation sequence of carbon-bearing condensates in circumstellar envelopes of carbon stars is (from first to last) TiC-graphite-SiC. We use thermochemical equilibrium condensation calculations and show that the condensation sequence of titanium carbide (TiC), graphite (C(Gr)), and silicon carbide (SiC) depends on metallicity in addition to C/O ratio and total pressure. Calculations were performed for a characteristic carbon star ratio of C/O = 1.2 from 10−10to 10−4bars total pressure and for uniform metallicity variations ranging from 0.01 to 100 times solar elemental abundances. TiC always condenses at higher temperatures than SiC, and the carbide condensation temperatures increase with both increasing metallicity and increasing total pressure. Graphite, however, can condense in a cooling circumstellar envelope before TiC, between TiC and SiC, or after SiC, depending on the carbon-bearing gas chemistry, which is dependent on metallicity and total pressure. Analytical expressions for the graphite, TiC, and SiC condensation temperatures as functions of metallicity and total pressure are presented. The inferred sequence from laboratory presolar grain studies, TiC-graphite-SiC, is favored under equilibrium conditions at solar and subsolar metallicities between ∼10−5and 10−8bar total pressure within circumstellar envelopes of carbon stars with nominal C/O = 1.2. We also explored the dependence of the sequence at C/O ratios of 1.1 and 3.0, and found that as the C/O ratio increases, the TiC-graphite-SiC condensation sequence region occurs toward higher total pressures and lower metallicities.
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This content will become publicly available on February 27, 2026
The Effects of the Carbon-to-oxygen Ratio on the Condensate Compositions around Solar-like Stars
Abstract The initial stellar carbon-to-oxygen (C/O) ratio can have a large impact on the resulting condensed species present in the protoplanetary disk and, hence, the composition of the bodies and planets that form. The observed C/Os of stars can vary from 0.1–1. We use a sequential dust condensation model to examine the impact of the C/O on the composition of solids around a solar-like star. We utilize this model in a focused examination of the impact of varying the initial stellar C/O to isolate the effects of the C/O in the context of solar-like stars. We describe three different system types in our findings. The solar system falls into the silicate-dominant, low-C/O systems which end at a stellar C/O somewhere between 0.52 and 0.6. At C/Os between about 0.6 and 0.9, we have intermediate systems. Intermediate systems show a decrease in silicates while carbides begin to become significant. Carbide-dominant systems begin around a C/O of 0.9. Carbide-dominant systems exhibit high carbide surface densities at inner radii with comparable levels of carbides and silicates at outer radii. Our models show that changes between C/O = 0.8 and C/O = 1 are more significant than previous studies, that carbon can exceed 80% of the condensed mass, and that carbon condensation can be significant at radii up to 6 au.
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- Award ID(s):
- 1910955
- PAR ID:
- 10638152
- Publisher / Repository:
- American Astronomical Society Journals
- Date Published:
- Journal Name:
- The Astronomical Journal
- Volume:
- 169
- Issue:
- 3
- ISSN:
- 0004-6256
- Page Range / eLocation ID:
- 180
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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