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For the past few decades, many researchers have sought to understand how tropical hydroclimate responds to climate change via lakes, marine sediments, and speleothems records. Speleothem δ18O records throughout South America have shown that regional rainfall responds to Northern Hemisphere forcing on the millennial scale. Areas under the influence of the South Atlantic Convergence Zone (SACZ) have also shown a close relationship with local insolation on longer timescales. However, apart from the Cruz et al. (2007) record in Southern Brazil, long-term speleothem records throughout the continent have relied primarily on stable oxygen isotopes and are therefore limited to describing large-scale regional variability in rainfall. As such, many areas in South America still lack long-term records of local hydroclimate, which is critical to understanding how different components of the monsoon system respond to orbital and millennial-scale climate change. One proxy that has gained more attention in recent years is trace metal-to-calcium ratios (TM/Ca). Sr, Mg, and Ba to Ca ratios in speleothems are known in certain situations to respond to the degree of Prior Calcite Precipitation (PCP) above a drip site, a phenomenon directly tied to local aridity. In this study, we have obtained high-resolution TM/Ca measurements to pair with stable isotopes from samples spanning 23 to 66 ka from Huagapo Cave in the Peruvian Andes (11.27°S; 75.79°W). TM/Ca ratios in these samples are strongly correlated (R2>0.89), making them suitable for use as PCP proxies. We see that decreases in δ18O during Heinrich events are accompanied by a drop in TM/Ca. The period defined by the MIS 4/3 transition is accompanied by a simultaneous increase in TM/Ca and δ18O. TM/Ca and δ18O negatively correlate with local insolation for the entire record. Interestingly, the Paraíso Cave record from the Amazon Basin shows no correlation between regional or local hydroclimate and insolation during the last glacial period. The discrepancy between the two records and the close relationship between TM/Ca, δ18O, and local insolation in Huagapo samples, may call for a revised interpretation of Andes speleothem δ18O variability, which was originally thought to reflect rainout over the Amazon Basin.
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NOAA/WDS Paleoclimatology - Hoa Huong Cave, Vietnam PCP-Corrected d18O Data from 4-45 ka
Oxygen isotopes (δ18O) are the most commonly utilized speleothem proxy and have provided many foundational records of paleoclimate. Thus, understanding processes affecting speleothem δ18O is crucial. Yet, prior calcite precipitation (PCP), a process driven by local hydrology, is a widely ignored control of speleothem δ18O. Here we investigate the effects of PCP on a stalagmite δ18O record from central Vietnam, spanning 45 – 4 ka. We employ a geochemical model that utilizes speleothem Mg/Ca and cave monitoring data to correct the δ18O record for PCP effects. The resulting record exhibits improved agreement with regional speleothem δ18O records and climate model simulations, suggesting that the corrected record more accurately reflects precipitation δ18O (δ18Op). Without considering PCP, our interpretations of the δ18O record would have been misleading. To avoid misinterpretations of speleothem δ18O, our results emphasize the necessity of considering PCP as a significant driver of speleothem δ18O.
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- Award ID(s):
- 2103129
- PAR ID:
- 10645278
- Publisher / Repository:
- NOAA National Centers for Environmental Information
- Date Published:
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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