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Title: 3D printing of pomelo-inspired piezoelectric composites
Abstract Traditional piezoelectric materials, such as lead zirconate titanate (PZT), are widely used due to their superior ability to convert mechanical energy into electrical energy. However, these lead-based ceramics are highly toxic and environmentally hazardous. This report explores Rochelle salt as an eco-friendly alternative, despite its brittleness and lower piezoelectric properties compared to PZT. The study investigates methods to enhance the energy capture of Rochelle salt crystals(RS) by varying crystal volume, impact frequency, and force, as well as by incorporating the 3D-printed biomimetic structure inspired by the pomelo fruit peel, which is naturally optimized for absorbing out-of-plane crushing forces. Experimental crystals grown within this structure were compared with those grown without it, focusing on energy capture and durability. Additionally, units with a 64:36 crystal-to-resin ratio were designed to assess the impact of crystal volume on voltage output. The experiments involved varying impact frequencies (120 rpm and 250 rpm) and compression distances (0.034 and 0.068 inches) using a digital oscilloscope and a custom crank slider mechanism. The results indicate that reducing crystal thickness and increasing rpms enhance voltage capture, suggesting that biomimetic structures can significantly improve the mechanical and electrical performance of piezoelectric materials. more »« less
Abstract Bionic multifunctional structural materials that are lightweight, strong, and perceptible have shown great promise in sports, medicine, and aerospace applications. However, smart monitoring devices with integrated mechanical protection and piezoelectric induction are limited. Herein, we report a strategy to grow the recyclable and healable piezoelectric Rochelle salt crystals in 3D-printed cuttlebone-inspired structures to form a new composite for reinforcement smart monitoring devices. In addition to its remarkable mechanical and piezoelectric performance, the growth mechanisms, the recyclability, the sensitivity, and repairability of the 3D-printed Rochelle salt cuttlebone composite were studied. Furthermore, the versatility of composite has been explored and applied as smart sensor armor for football players and fall alarm knee pads, focusing on incorporated mechanical reinforcement and electrical self-sensing capabilities with data collection of the magnitude and distribution of impact forces, which offers new ideas for the design of next-generation smart monitoring electronics in sports, military, aerospace, and biomedical engineering.
Chen, Shuai; He, Qingqing; Yang, Yang; Xu, Han
(, American Society of Mechanical Engineers)
Abstract This study explores a novel multi-material 3D printing technique for fabricating bioinspired hydrogel-Rochelle salt composites, focusing on optimizing concentration, cooling, and coating parameters to enhance material performance. The hydrogel-Rochelle salt composite is a promising material due to its lightweight, mechanical robustness, and piezoelectric properties, making it suitable for applications in sensors, medical devices, and structural materials. A series of concentration tests was conducted to determine the optimal Rochelle salt concentration for achieving efficient curing depth and exposure time. The results identified 50wt% hydrogel/50wt% Rochelle salt as the optimal concentration, providing a balanced curing profile essential for ensuring reliable layer adhesion and structural consistency. To enable controlled crystallization, a cooling process was introduced, with a cooling time of 15 minutes found to be sufficient for complete crystallization to a depth of 500 microns. Thermal imaging and microscopy confirmed the stability of the crystalline structure within the hydrogel matrix, ensuring the material’s functional integrity. Additionally, applying a coating to the printed structure significantly improved surface uniformity and durability, embedding the crystalline elements more effectively within the hydrogel matrix and enhancing the composite’s overall structural integrity. This coating process allowed the composite to withstand repeated printing cycles, facilitating the construction of layered, multi-material structures with improved mechanical and functional properties. The results highlight the importance of fine-tuning concentration, cooling time, and coating techniques to achieve optimal performance in multi-material 3D printing. By addressing these factors, the study demonstrates a reliable approach to producing hydrogel-Rochelle salt composites with high structural quality and piezoelectric functionality. This method not only enhances the material’s durability and adhesion between layers but also opens new possibilities for creating customized, multifunctional materials. The developed process holds significant promise for applications that require precise control over material properties, such as wearable electronics, medical implants, and lightweight structural components. In conclusion, this research provides valuable insights into the fabrication of hydrogel-Rochelle salt composites through advanced 3D printing techniques. The findings offer a foundation for future exploration in multi-material printing and composite fabrication, paving the way for the development of versatile materials with tailored properties for diverse applications.
Abstract Converting mechanical energy from either the ambient environment or the human body motions to the useful electrical energy will revolutionize power solutions for flexible electronics. Here, a hybrid energy harvesting strategy is reported, which combines porous polymeric piezoelectric film with an electrostatic layer as an integration for converting the mechanical energy into electrical energy. The piezoelectric materials through engineered microstructures are developed to enhance energy generation due to the higher compressibility and larger surface contact area. The electrostatic effect from the charged layer further contributes to the generation of electrical charges. By directly coating the stretchable carbon nanotubes onto the elastomers, more intimate integration of the hybrid energy harvesters enables the designs for complex electronics. Such flexible hybrid piezoelectric‐electrostatic device exhibits superior energy harvesting performance with a voltage output of 1.95 V, which improves 30% and 100% compared to the electrostatic and piezoelectric alone device, respectively. Experiments are also performed to demonstrate the implementation of the hybrid device's energy conversion to power small electronics and recognition of different body motions. Such hybrid strategy provides a new solution toward future energy revolution for flexible electronics.
High-performance piezoelectrics benefit transducers and sensors in a variety of electromechanical applications.The materials with the highest piezoelectric chargecoefficients (d33) are relaxor-PbTiO3 crystals, which were discovered two decades ago. We successfully grew Sm-doped Pb(Mg1/3Nb2/3)O3-PbTiO3 (Sm-PMN-PT) single crystals with even higher d33 values ranging from 3400 to 4100 picocoulombs per newton, with variation below 20%over the as-grown crystal boule, exhibiting good property uniformity. We characterized the Sm-PMN-PTon the atomic scale with scanning transmission electron microscopy and made first-principles calculations to determine that the giant piezoelectric properties arise fromthe enhanced local structural heterogeneity introduced by Sm3+ dopants. Rare-earth doping is thus identified as a general strategy for introducing local structural heterogeneity in order to enhance the piezoelectricity of relaxor ferroelectric crystals.
Abstract Achieving substantial electrostrain alongside a large effective piezoelectric strain coefficient (d33*) in piezoelectric materials remains a formidable challenge for advanced actuator applications. Here, a straightforward approach to enhance these properties by strategically designing the domain structure and controlling the domain switching through the introduction of arrays of ordered {100}<100> dislocations is proposed. This dislocation engineering yields an intrinsic lock‐in steady–state electrostrain of 0.69% at a low field of 10 kV cm−1without external stress and an output strain energy density of 5.24 J cm−3in single‐crystal BaTiO3, outperforming the benchmark piezoceramics and relaxor ferroelectric single‐crystals. Additionally, applying a compression stress of 6 MPa fully unlocks electrostrains exceeding 1%, yielding a remarkabled33* value over 10 000 pm V−1and achieving a record‐high strain energy density of 11.67 J cm−3. Optical and transmission electron microscopy, paired with laboratory and synchrotron X‐ray diffraction, is employed to rationalize the observed electrostrain. Phase‐field simulations further elucidate the impact of charged dislocations on domain nucleation and domain switching. These findings present an effective and sustainable strategy for developing high‐performance, lead‐free piezoelectric materials without the need for additional chemical elements, offering immense potential for actuator technologies.
@article{osti_10645616,
place = {Country unknown/Code not available},
title = {3D printing of pomelo-inspired piezoelectric composites},
url = {https://par.nsf.gov/biblio/10645616},
DOI = {10.1088/1402-4896/ade34a},
abstractNote = {Abstract Traditional piezoelectric materials, such as lead zirconate titanate (PZT), are widely used due to their superior ability to convert mechanical energy into electrical energy. However, these lead-based ceramics are highly toxic and environmentally hazardous. This report explores Rochelle salt as an eco-friendly alternative, despite its brittleness and lower piezoelectric properties compared to PZT. The study investigates methods to enhance the energy capture of Rochelle salt crystals(RS) by varying crystal volume, impact frequency, and force, as well as by incorporating the 3D-printed biomimetic structure inspired by the pomelo fruit peel, which is naturally optimized for absorbing out-of-plane crushing forces. Experimental crystals grown within this structure were compared with those grown without it, focusing on energy capture and durability. Additionally, units with a 64:36 crystal-to-resin ratio were designed to assess the impact of crystal volume on voltage output. The experiments involved varying impact frequencies (120 rpm and 250 rpm) and compression distances (0.034 and 0.068 inches) using a digital oscilloscope and a custom crank slider mechanism. The results indicate that reducing crystal thickness and increasing rpms enhance voltage capture, suggesting that biomimetic structures can significantly improve the mechanical and electrical performance of piezoelectric materials.},
journal = {Physica Scripta},
volume = {100},
number = {7},
publisher = {IOP Publishing Ltd},
author = {Kassab, Destiny and Hodgson, Michael and Ly, Tran and Pinuelas, Tyler and Xie, Nathan and Zhu, Yihe and Dee, Zaiden and Wu, Wenhao and Zhao, Zeyuan and Chen, Shuai and He, Qingqing and Yang, Yang},
}
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