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This content will become publicly available on May 15, 2026

Title: Reactive thermodynamics of crustal eclogitization and foundering
Regional metamorphism and densification (eclogitization) of the lower crust can affect the lithospheric dynamics of mountain belts, but the coupled effects of reaction rate, temperature, and composition on metamorphism are poorly understood. We present a reactive thermodynamic model of the granulite–eclogite transition to investigate the long-term buoyancy and gravitational stability of the lower crust. First, we characterize the conditions for which orogenic crust attains negative buoyancy by determining its reactive mineral assemblage and density under prescribed pressure–temperature–time paths. Using existing metamorphic rate data, we calibrate a Damkoḧler number (a relative reaction rate) to parameterize the catalytic effect of aqueous fluids. The depth necessary for negative buoyancy is sensitive to temperature and Da, ranging from ∼45 to Image 1 for a basaltic-andesite composition (54 wt.% SiO2). Second, using a Rayleigh–Taylor instability analysis, we suggest that, while cold eclogitic crusts Image 2 could obtain large thicknesses of ∼10 to Image 3 and would founder within Image 4. We hypothesize that such foundering events are a natural consequence of convergent tectonics, where the aqueous fluids and high pressures required for metamorphism are known to exist. The Pampean flat slab in the Central Andes provides geophysical evidence linking slab fluids to eclogitization and densification of the thickened continental crust. Lithospheric foundering coupled to convergent tectonics through eclogitization could explain many observations of orogenic hinterland deformation and magmatism.  more » « less
Award ID(s):
2323318
PAR ID:
10647644
Author(s) / Creator(s):
; ;
Publisher / Repository:
Elsevier
Date Published:
Journal Name:
Earth and planetary science letters
Volume:
658
ISSN:
0012-821X
Subject(s) / Keyword(s):
Eclogite Granulite Orogeny Geodynamics High pressure metamorphism
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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