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Title: The ICOS OTCpCO2 instrument intercomparison
Abstract In 2021, the Ocean Thematic Centre of the European Research Infrastructure “Integrated Carbon Observation System” conducted an international partial pressure of carbon dioxide (pCO2) instrument intercomparison. The goal was to understand how different types of instrumentation for the measurement of oceanpCO2compare to each other. During the two‐week long experiment, we installed various instruments in a tank facility using natural sea water (North Sea). These included direct air–water equilibration systems and membrane‐based flow‐through instruments along with submersible sensors and instruments that are normally installed on buoys and autonomous surface vehicles. In situ instruments were installed inside the tank and the flow‐through instruments were fed the same water using a pumping system. We changed the temperature (between 10°C and 28°C) and the seawaterpCO2(between 250 and 800μatm) to observe instrument responses over a wide range. Since there is no reference for surface oceanpCO2measurements, we agreed on a set of instruments serving as intercomparison reference. All data from the different instruments were then compared against the intercomparison reference during periods of stable temperature andpCO2. The study provides important information to enhance future ocean carbon monitoring networks, but makes no direct recommendation for the use of any specific sensor. A major finding is that equilibration through direct air–water contact appears to be more consistent and independent of external factors than equilibration through a membrane or photometric detection. We found several instruments with no temperature measurements at the location of equilibration or with uncalibrated temperature sensors introducing significant uncertainty in the results.  more » « less
Award ID(s):
2140395
PAR ID:
10648547
Author(s) / Creator(s):
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Publisher / Repository:
Wiley
Date Published:
Journal Name:
Limnology and Oceanography: Methods
ISSN:
1541-5856
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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