skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


This content will become publicly available on October 17, 2026

Title: Earth’s core-mantle differentiation shaped by water
Earth’s core-mantle segregation set the initial conditions for its subsequent evolution. However, the effect of water on core-mantle element partitioning remains poorly constrained. Using machine learning molecular dynamics simulations trained on quantum mechanical data, we show that increasing water content promotes magnesium partitioning into the metallic core, whereas silicon, iron, and hydrogen increasingly prefer the silicate mantle. On the basis of Earth’s core mass fraction and oxygen fugacity during core formation, a self-consistent hydrous core-mantle differentiation model yields a bulk Earth water content of ~0.23 weight % (equivalently ~10 ocean masses), a bulk Earth magnesium/silicon ratio of 1.16 ± 0.01, and a mantle magnesium/silicon ratio of 1.25 to 1.28. The initial core would contain 3.5 to 4.1 weight % silicon, 2.9 to 3.1 weight % oxygen, 0.11 to 0.14 weight % magnesium, and 0.04 to 0.10 weight % hydrogen, along with sulfur and carbon. We predict that super-Earths can retain large metallic cores even with several weight % water.  more » « less
Award ID(s):
2444522
PAR ID:
10651406
Author(s) / Creator(s):
; ;
Publisher / Repository:
American Association for the Advancement of Science
Date Published:
Journal Name:
Science Advances
Volume:
11
Issue:
42
ISSN:
2375-2548
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract Terrestrial planets (Mercury, Venus, Earth, and Mars) are differentiated into three layers: a metallic core, a silicate shell (mantle and crust), and a volatile envelope of gases, ices, and, for the Earth, liquid water. Each layer has different dominant elements (e.g., increasing iron content with depth and increasing oxygen content to the surface). Chondrites, the building blocks of the terrestrial planets, have mass and atomic proportions of oxygen, iron, magnesium, and silicon totaling ≥ 90% and variable Mg/Si (∼ 25%), Fe/Si (factor of ≥2), and Fe/O (factor of ≥ 3). What remains an unknown is to what degree did physical processes during nebular disk accretion versus those during post-nebular disk accretion (e.g., impact erosion) influence these planets final bulk compositions. Here we predict terrestrial planet compositions and show that their core mass fractions and uncompressed densities correlate with their heliocentric distance, and follow a simple model of the magnetic field strength in the protoplanetary disk. Our model assesses the distribution of iron in terms of increasing oxidation state, aerodynamics, and a decreasing magnetic field strength outward from the Sun, leading to decreasing core size of the terrestrial planets with radial distance. This distribution enhances habitability in our solar system and may be equally applicable to exoplanetary systems. 
    more » « less
  2. Abstract High pressure and temperature experiments were carried out on the oxide mixtures corresponding to the bridgmanite stoichiometry under the hydrous shallow lower mantle conditions (24–25 GPa and 1673–1873 K with 5–10 wt. % of water in the starting material). Oxide mixtures investigated correspond to MgSiO3, (Mg, Fe)SiO3, (Mg, Al, Si)O3, and (Mg, Fe, Al, Si)O3. Melting was observed in all runs. Partitioning of various elements, including Mg, Fe, Si, and H is investigated. Melting under hydrous lower mantle conditions leads to increased (Mg + Fe)O/SiO2in the melt compared to the residual solids. The residual solids often contain a large amount of stishovite, and the melt contains higher (Mg,Fe)O/SiO2ratio than the initial material. (Mg + Fe)O‐rich hydrous melt could explain the low‐velocity anomalies observed in the shallow lower mantle and a large amount of stishovite in the residual solid may be responsible for the scattering of seismic waves in the mid‐lower mantle and may explain the “stishovite paradox. Since stishovite‐rich materials are formed only when silica‐rich source rock (MORB) is melted (not a typical peridotitic rock [bulk silicate Earth]), seismic scattering in the lower mantle provides a clue on the circulation of subducted MORB materials. To estimate hydrogen content, we use a new method of estimating the water content of unquenchable melts, and also propose a new interpretation of the significance of superhydrous phase B inclusions in bridgmanite. The results provide revised values of water partitioning between solid minerals and hydrous melts that are substantially higher than previous estimates. 
    more » « less
  3. Abstract Earth's core has produced a global magnetic field for at least the last 3.5 Gyrs, presently sustained by inner core (IC) growth. Models of the core with high thermal conductivity suggest potentially insufficient power available for the geodynamo prior to IC formation ∼1 Ga. Precipitation of silicon from the liquid core might offer an alternative power source for the ancient magnetic field, although few estimates of the silicon partition coefficient exist for conditions of the early core. We present the first ab initio determination of the silicon partition coefficient at core‐mantle boundary conditions and use these results to confirm a thermodynamic description of partitioning that is integrated into a model of coupled core‐mantle thermal evolution. We show that models including precipitation of silicon can satisfy constraints of IC size, mantle convective heat flux, mantle temperature and a persistent ancient geodynamo, and favor an oxygen poor initial core composition. 
    more » « less
  4. The Earth’s mantle transition zone (MTZ) is often considered an internal reservoir for water because its major minerals wadsleyite and ringwoodite can store several oceans of structural water. Whether it is a hydrous layer or an empty reservoir is still under debate. Previous studies suggested the MTZ may be saturated with iron metal. Here we show that metallic iron reacts with hydrous wadsleyite under the pressure and temperature conditions of the MTZ to form iron hydride or molecular hydrogen and silicate with less than tens of parts per million (ppm) water, implying that water enrichment is incompatible with iron saturation in the MTZ. With the current estimate of water flux to the MTZ, the iron metal preserved from early Earth could transform a significant fraction of subducted water into reduced hydrogen species, thus limiting the hydration of silicates in the bulk MTZ. Meanwhile, the MTZ would become gradually oxidized and metal depleted. As a result, water-rich region can still exist near modern active slabs where iron metal was consumed by reaction with subducted water. Heterogeneous water distribution resolves the apparent contradiction between the extreme water enrichment indicated by the occurrence of hydrous ringwoodite and ice VII in superdeep diamonds and the relatively low water content in bulk MTZ silicates inferred from electrical conductivity studies. 
    more » « less
  5. unknown (Ed.)
    The Earth’s core–mantle boundary presents a dramatic change in materials, from silicate to metal. While little is known about chemical interactions between them, a thin layer with a lower velocity has been proposed at the topmost outer core (Eʹ layer) that is difficult to explain with a change in concentration of a single light element. Here we perform high-temperature and -pressure laser-heated diamond-anvil cell experiments and report the formation of SiO2 and FeHx from a reaction between water from hydrous minerals and Fe–Si alloys at the pressure–temperature conditions relevant to the Earth’s core–mantle boundary. We suggest that, if water has been delivered to the core–mantle boundary by subduction, this reaction could enable exchange of hydrogen and silicon between the mantle and the core. The resulting H-rich, Si-deficient layer formed at the topmost core would have a lower density, stabilizing chemical stratification at the top of the core, and a lower velocity. We suggest that such chemical exchange between the core and mantle over gigayears of deep transport of water may have contributed to the formation of the putative Eʹ layer. 
    more » « less