Customized membranes: needs and opportunities for moving beyond conventional interfacial polymerization for desalination membranes

Hacıfazlıoğlu, Mert Can; Ahmadipouya, Salman; Ipekci, Deniz; Li, Ying; Kumar, Manish; Warner, Jamie; Zhang, Yuepeng; McCutcheon, Jeffrey R (ORCID:0000000256384926)

doi:10.1016/j.coche.2025.101151

Polyamide thickness and roughness have been identified as critical properties that affect thin-film composite membrane performance for reverse osmosis. Conventional formation methodologies lack the ability to control these properties independently with high resolution or precision. An additive approach is presented that uses electrospraying to deposit monomers directly onto a substrate, where they react to form polyamide. The small droplet size coupled with low monomer concentrations result in polyamide films that are smoother and thinner than conventional polyamides, while the additive nature of the approach allows for control of thickness and roughness. Polyamide films are formed with a thickness that is controllable down to 4-nanometer increments and a roughness as low as 2 nanometers while still exhibiting good permselectivity relative to a commercial benchmarking membrane.

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