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Abstract Smart materials with coupled optical and mechanical responsiveness to external stimuli, as inspired by nature, are of interest for the biomimetic design of the next generation of soft machines and wearable electronics. A tough polymer that shows adaptable and switchable mechanical and fluorescent properties is designed using a fluorescent lanthanide, europium (Eu). The dynamic Eu‐iminodiacetate (IDA) coordination is incorporated to build up the physical cross‐linking network in the polymer film consisting of two interpenetrated networks. Reversible disruption and reformation of Eu‐IDA complexation endow high stiffness, toughness, and stretchability to the polymer elastomer through energy dissipation of dynamic coordination. Water that binds to Eu3+ions shows an interesting impact simultaneously on the mechanical strength and fluorescent emission of the Eu‐containing polymer elastomer. The mechanical states of the polymer, along with the visually optical response through the emission color change of the polymer film, are reversibly switchable with moisture as a stimulus. The coupled response in the mechanical strength and emissive color in one single material is potentially applicable for smart materials requiring an optical readout of their mechanical properties.
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This content will become publicly available on June 1, 2026
Double-network-inspired mechanical metamaterials
Mechanical metamaterials are renowned for their ability to achieve high stiffness and strength at low densities, often at the expense of low ductility and stretchability-a persistent trade-off in materials. In contrast, materials such as double-network hydrogels feature interpenetrating compliant and stiff polymer networks, and exhibit unprecedented combinations of high stiffness and stretchability, resulting in exceptional toughness. Here, we present double-network-inspired (DNI) metamaterials by integrating monolithic truss (stiff) and woven (compliant) components into a metamaterial architecture, which achieve a tenfold increase in stiffness and stretchability compared to their pure woven and truss counterparts, respectively. Nonlinear computational mechanics models elucidate that enhanced energy dissipation in these DNI metamaterials stems from increased frictional dissipation due to entanglements between the two networks. Through introduction of internal defects, which typically degrade mechanical properties, we demonstrate an opposite effect of a threefold increase in energy dissipation for these metamaterials via failure delocalization. This work opens avenues for developing new classes of metamaterials in a high-compliance regime inspired by polymer network topologies.
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- PAR ID:
- 10655856
- Publisher / Repository:
- Nature Springer
- Date Published:
- Journal Name:
- Nature Materials
- Volume:
- 24
- Issue:
- 6
- ISSN:
- 1476-1122
- Page Range / eLocation ID:
- 945 to 954
- Subject(s) / Keyword(s):
- metamaterials entanglement woven lattices double networks
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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