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Half a century since the photocatalytic disproportionation of Lappert's dialkyl stannylene SnR 2 , R = CH(SiMe 3 ) 2 (1) gave the persistent trivalent radical [·SnR 3 ], the characterization of the corresponding Sn(I) product, ·SnR is now described. It was isolated as the hexastannaprismane Sn 6 R 6 (2), from the reduction of 1 by the Mg(I)-reagent, Mg(BDI Dip ) 2 , (BDI = (DipNCMe) 2 CH, Dip + 2,6-diisopropylphenyl).
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Compounds with Chelating 3-Dimethylamino-1-propyl Ligands as Chemical Vapor Deposition Precursors. Synthesis and Characterization of M[(CH 2 ) 3 NMe 2 ] 2 Complexes of Nickel(II), Palladium(II), and Platinum(II)
- Award ID(s):
- 2400099
- PAR ID:
- 10656982
- Publisher / Repository:
- American Chemical Society
- Date Published:
- Journal Name:
- Organometallics
- Volume:
- 43
- Issue:
- 20
- ISSN:
- 0276-7333
- Page Range / eLocation ID:
- 2548 to 2556
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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High-resolution X-ray diffraction experiments, theoretical calculations and atom-specific X-ray absorption experiments were used to investigate two nickel complexes, (MePh 3 P) 2 [Ni II (bdtCl 2 ) 2 ]·2(CH 3 ) 2 SO [complex (1)] and (MePh 3 P)[Ni III (bdtCl 2 ) 2 ] [complex (2)]. Combining the techniques of nickel K - and sulfur K -edge X-ray absorption spectroscopy with high-resolution X-ray charge density modeling, together with theoretical calculations, the actual oxidation states of the central Ni atoms in these two complexes are investigated. Ni ions in two complexes are clearly in different oxidation states: the Ni ion of complex (1) is formally Ni II ; that of complex (2) should be formally Ni III , yet it is best described as a combination of Ni 2+ and Ni 3+ , due to the involvement of the non-innocent ligand in the Ni— L bond. A detailed description of Ni—S bond character (σ,π) is presented.more » « less
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1021/acs.organomet.4c00186
