skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: A modular flat-flame experimental platform for mechanistic studies of plasma-assisted ammonia-methane combustion
Recent efforts to reduce emissions of NOx, N2O, and NH3-slip in ammonia-methane (NH3/CH4) combustion using Nanosecond Repetitively Pulsed Discharges (NRPD) have relied largely on complex plasma-assisted combustion experiments in three-dimensional, turbulent, swirl-stabilized burners. In this work, we introduce a modular experimental platform based on a flat-flame McKenna burner to isolate and study the fundamental plasma-flame interactions that govern NRPD-assisted combustion of NH3/CH4/air mixtures. The burner-plasma assembly supports both nanosecond-spark and uniform-discharge operating modes when generating the plasma in the hot exhaust gases. Preliminary NO measurements, with NRPD applied either in the post-flame region or directly within the reaction zone, indicate a net NO penalty under the conditions tested. These results highlight the need for further mechanistic investigation of NRPD-driven chemistry in ammonia-methane flames and its implications for emissions reduction strategies.  more » « less
Award ID(s):
2339518
PAR ID:
10661573
Author(s) / Creator(s):
; ; ;
Publisher / Repository:
AIAA SciTech 2026 Forum
Date Published:
Format(s):
Medium: X
Location:
https://arc.aiaa.org/doi/abs/10.2514/6.2026-0164
Sponsoring Org:
National Science Foundation
More Like this
  1. In this paper we explore the effects of nanosecond repetitively pulsed discharges (NRPD) on combustion instabilities and NOx emissions of CH4/NH3 flames, in a swirl-stabilized, 6 kW combustor. The combustor has a large dump plane ratio resulting in a turbulent flame with a single compact macrostructure across all operating conditions. Discharges are setup with a central pin-to-cylindrical-wall type electrode configuration with a discharge gap of 4.55 mm at the dump plane. For pure methane, instabilities occur at various frequencies and amplitudes, up to 1000 Pa. NPRD actuation was successful in suppressing instabilities across all conditions, with best reduction being as much as 23 dB. The discharge voltages ranged from 6-9 kV at a pulse rate of 9 kHz, equivalent to 5-12 mJ/pulse energies and plasma powers less than 99W. For pure CH4 flames, the NRPD actuation increased NOx emissions, but for high NH3/CH4 blends, the NRPD actuation reduced NOx emissions. 
    more » « less
  2. Plasma-assisted combustion of ammonia leverages non-equilibrium electrical discharges to modify flame dynamics and emissions. In this work, we perform a numerical investigation using a one-dimensional model to examine the influence of nanosecond-repetitively pulsed discharges on the propagation of stoichiometric ammonia-air flames at atmospheric conditions. The model incorporates detailed plasma chemistry solved with ZDPlasKin. In particular, we look into the influence of pulse repetition frequency on laminar flame speed and NOx emissions. The simulations reveal unexpected behavior in the spatial distribution of plasma energy deposition within the flame. The plasma is found to significantly speed up the flame, up to +140%, although some numerical challenges prevented us from exploring operation at higher frequencies. The chemical kinetics used also predict a small decrease in š‘š‘‚ in the product region of the flame. 
    more » « less
  3. Pepiot, Perrine (Ed.)
    The Global Pathway Analysis (GPA) algorithm helps analyze the chemical kinetics of complex combustion systems by identifying important global reaction pathways connecting a source species to a sink species through various important intermediate species (i.e., hub species). The present work aims to extend GPA algorithm to plasma-assisted combustion and fuel reforming systems to identify the dominant global pathways in such systems at various conditions. In addition, the present study extends the ability of GPA algorithm to identify reaction cycles involving the excitation of high-concentration species (e.g., O2, N2, and fuel) to their vibrational and electronic states and the subsequent de-excitation to their ground state, based on their significance on the reactivity of plasma-assisted systems in terms of gas heating and radical production. Provisions are made in the GPA algorithm to evaluate the reactivity of identified reaction pathways and cycles based on the element-flux transfer (i.e., dominance), heat release, and radical production rate. The newly developed Plasma-based Global Pathway Analysis (PGPA) algorithm is then used to analyze the plasma-assisted combustion of ammonia and reforming of methane. The PGPA analyses elucidated the significance of vibrational-translational cycles on the reactivity of NH3/air mixtures. Further, analyses on the production of NO ascribed the early reforming of NH3 to N2 and H2 in impeding the production of NO during plasma-assisted NH3 ignition. Lastly, the enhanced reforming of CH4/N2 mixtures using plasma has been attributed to electron impact dissociation of CH4 when compared to thermal reforming. In contrast, conventional path-Flux analysis (PFA) was found to require significant manual effort and pre-analysis intuitions from expert knowledge, making it arduous to provide valuable insights into plasma chemistry. The user-friendly and automated nature of PGPA thus provides a valuable tool for assessing the kinetics of plasma-assisted systems helpful in analyzing and, further, a foundation in reducing plasma-assisted chemistry, without the needs of expert knowledge. 
    more » « less
  4. This work aims at studying the combustion and pyrolysis characteristics of ammonia (NH3) using non-equilibrium plasma. The well known challenges of ammonia combustion and the advantages of using non-equilibrium plasma are discussed using results of zero-dimensional and one-dimensional coupled simulations. Periodic nanosecond pulsed discharges of plasma are interspersed with microsecond gaps of combustion to assess the assistance provided by plasma on overall combustion characteristics of ammonia fuel, such as ignition delay and flammability limit. Due to the lack of a reliable plasma mechanism for ammonia, a validated plasma kinetic mechanism of methane and oxygen is transformed to that of ammonia and oxygen, and is coupled with an experimentally validated ammonia combustion mechanism in this work. Another NH3 / O2 / He plasma mechanism that was recently assembled and published is also used to study the discharge and inter-pulse kinetics. A 0D model is developed to compute the rates of the electron impact reactions during the discharge, and ion-electron recombination reactions and quenching reactions along with the combustion reactions during the gap. Finally, the species concentrations and temperatures from this model are compared with those obtained using a detailed 1D model which solves for the transient electric field in addition to the species concentrations and temperature. 
    more » « less
  5. This paper systematically evaluates how, and to what extent, nanosecond repetitively pulsed (NRP) discharges modify the laminar flame speed of methane–air mixtures at ambient conditions, using both experiments in a narrow-channel quartz burner and a one-dimensional plasma-combustion model described in an accompanying paper (Part I). By varying the discharge location relative to the flame, four actuation strategies were explored at variable pulse repetition frequency: (i) discharges far ahead of the flame, (ii) pre-treatment of fresh reactants, (iii) direct (insitu) plasma–flame overlap, and (iv) a combination of pre-treatment and insitu interaction. Results show that acoustic waves produced by upstream discharges can reduce flame speed by as much as 30%–40%; while partially overlapping the discharge with the flame significantly accelerates it, with measured enhancements of up to 50% in both model and experiment. Flame speed modification by plasma increased with pulse repetition frequency, so that the envelope of performance enhancement reported here is limited by the highest frequencies tested (8kHz). The model captures these trends by attributing the detrimental effects to pressure-wave disturbances and the beneficial effects to radical-seeding and mild heat addition in, and close to, the reaction zone. These observations may help shed light on previously reported experiments and are here presented in a unified manner by focusing on a fundamental combustion metric (laminar flame speed), to give generality to the results obtained in laminar flames. The results demonstrate how spatio-temporal positioning of the discharge governs whether plasma aids or hinders the flame, ultimately guiding the design of optimal plasma-assisted combustion strategies. 
    more » « less