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57Fe nuclear resonance vibrational spectroscopic studies of tetranuclear iron clusters bearing terminal iron(III)–oxido/hydroxido moieties

https://doi.org/10.1039/d4sc03396e

Xiong, Jin; Reed, Christopher; Lavina, Barbara; Hu, Michael Y; Zhao, Jiyong; Alp, Esen E; Agapie, Theodor; Guo, Yisong (October 2024, Chemical Science)

57Fe nuclear resonance vibrational spectroscopy (NRVS) is used to study the tetranuclear iron clusters bearing a terminal Fe(iii)–O/OH moiety. The redox states of the three remote basal iron sites modulate the Fe(iii)–O/OH vibrational frequencies.
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Free, publicly-accessible full text available October 9, 2025
Redox Processes Involving Oxygen: The Surprising Influence of Redox-Inactive Lewis Acids

https://doi.org/10.1021/jacsau.3c00675

Lionetti, Davide; Suseno, Sandy; Shiau, Angela A; de_Ruiter, Graham; Agapie, Theodor (January 2024, JACS Au)

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Molybdenum-Mediated Coupling of Carbon Monoxide to a C ₃ Product on a Single Metal Site

https://doi.org/10.1021/acs.inorgchem.2c00266

Low, Choon Heng; Buss, Joshua A.; Agapie, Theodor (May 2022, Inorganic Chemistry)

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Terminal Mo Carbide and Carbyne Reactivity: H ₂ Cleavage, B–C Bond Activation, and C–C Coupling

https://doi.org/10.1021/acs.organomet.1c00336

Bailey, Gwendolyn A.; Agapie, Theodor (August 2021, Organometallics)
null (Ed.)
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Carbon Dioxide Reduction with Dihydrogen and Silanes at Low-Valent Molybdenum Terphenyl Diphosphine Complexes: Reductant Identity Dictates Mechanism

https://doi.org/10.1021/acscatal.1c02922

Buss, Joshua A.; Shida, Naoki; He, Tianyi; Agapie, Theodor (November 2021, ACS Catalysis)

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Terminal, Open-Shell Mo Carbide and Carbyne Complexes: Spin Delocalization and Ligand Noninnocence

https://doi.org/10.1021/jacs.1c03806

Bailey, Gwendolyn A.; Buss, Joshua A.; Oyala, Paul H.; Agapie, Theodor (August 2021, Journal of the American Chemical Society)
null (Ed.)
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Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer

https://doi.org/10.1039/D2CC00473A

Mazzanti, Marinella; Barluzzi, Luciano; Jori, Nadir; Maron, Laurent; Scopelliti, Rosario; Oyala, Paul; Agapie, Theodor; He, Tianyi; Rajeshkumar, Thayalan (January 2022, Chemical Communications)

The reaction of a terminal Mo(II) nitride with a U(III) complex yields an heterodimetallic U-Mo nitride which is the first example of a transition metal-capped uranium nitride. The nitride is triply bonded to U(V) and singly bonded to Mo(0) and supports a U-Mo interaction. This compound shows reactivity toward CO oxidation.
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Activation of an Open Shell, Carbyne-Bridged Diiron Complex Toward Binding of Dinitrogen

https://doi.org/10.1021/jacs.0c01896

Arnett, Charles H.; Agapie, Theodor (June 2020, Journal of the American Chemical Society)

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A hemilabile diphosphine pyridine pincer ligand: σ- and π-binding in molybdenum coordination complexes

https://doi.org/10.1016/j.poly.2020.114631

Wan, Ruomeng; Buss, Joshua A.; Horak, Kyle T.; Agapie, Theodor (September 2020, Polyhedron)
null (Ed.)
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Mixed-Valent Diiron μ-Carbyne, μ-Hydride Complexes: Implications for Nitrogenase

https://doi.org/10.1021/jacs.0c05920

Arnett, Charles H.; Bogacz, Isabel; Chatterjee, Ruchira; Yano, Junko; Oyala, Paul H.; Agapie, Theodor (November 2020, Journal of the American Chemical Society)
null (Ed.)
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