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Kinetic Profiles as a Diagnostic Probe of Complex Multi-Cycle Catalytic Reaction Networks

https://doi.org/10.1021/acs.joc.5c00940

Deng, Min; Blackmond, Donna G (September 2025, The Journal of Organic Chemistry)

Free, publicly-accessible full text available September 2, 2026
In Situ Kinetic Studies of Rh(II)-Catalyzed C–H Functionalization to Achieve High Catalyst Turnover Numbers

https://doi.org/10.1021/acscatal.2c04115

Wei, Bo; Sharland, Jack C.; Blackmond, Donna G.; Musaev, Djamaladdin G.; Davies, Huw M. (November 2022, ACS Catalysis)

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Mechanistic Insight into Cu-Catalyzed C–N Coupling of Hindered Aryl Iodides and Anilines Using a Pyrrol-ol Ligand Enables Development of Mild and Homogeneous Reaction Conditions

https://doi.org/10.1021/acscatal.2c06201

de Gombert, Antoine; Darù, Andrea; Ahmed, Tonia S.; Haibach, Michael C.; Li-Matsuura, Rei; Yang, Cassie; Henry, Rodger F.; Cook, Silas P.; Shekhar, Shashank; Blackmond, Donna G. (March 2023, ACS Catalysis)

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Electrochemical borylation of carboxylic acids

https://doi.org/10.1073/pnas.2109408118

Barton, Lisa M.; Chen, Longrui; Blackmond, Donna G.; Baran, Phil S. (August 2021, Proceedings of the National Academy of Sciences)

A simple electrochemically mediated method for the conversion of alkyl carboxylic acids to their borylated congeners is presented. This protocol features an undivided cell setup with inexpensive carbon-based electrodes and exhibits a broad substrate scope and scalability in both flow and batch reactors. The use of this method in challenging contexts is exemplified with a modular formal synthesis of jawsamycin, a natural product harboring five cyclopropane rings.
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Insights into the Role of Transient Chiral Mediators and Pyridone Ligands in Asymmetric Pd-Catalyzed C–H Functionalization

https://doi.org/10.1021/acs.joc.0c01798

Hill, David E.; Yu, Jin-Quan; Blackmond, Donna G. (November 2020, The Journal of Organic Chemistry)
null (Ed.)
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Electrochemical Nozaki–Hiyama–Kishi Coupling: Scope, Applications, and Mechanism

https://doi.org/10.1021/jacs.1c03007

Gao, Yang; Hill, David E.; Hao, Wei; McNicholas, Brendon J.; Vantourout, Julien C.; Hadt, Ryan G.; Reisman, Sarah E.; Blackmond, Donna G.; Baran, Phil S. (June 2021, Journal of the American Chemical Society)
null (Ed.)
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Probing Catalyst Speciation in Pd-MPAAM-Catalyzed Enantioselective C(sp ³ )–H Arylation: Catalyst Improvement via Destabilization of Off-Cycle Species

https://doi.org/10.1021/acscatal.1c02805

Hao, Wei; Bay, Katherine L.; Harris, Caleb F.; King, Daniel S.; Guzei, Ilia A.; Aristov, Michael M.; Zhuang, Zhe; Plata, R. Erik; Hill, David E.; Houk, K. N.; et al (September 2021, ACS Catalysis)

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Cobalt-electrocatalytic HAT for functionalization of unsaturated C–C bonds

https://doi.org/10.1038/s41586-022-04595-3

Gnaim, Samer; Bauer, Adriano; Zhang, Hai-Jun; Chen, Longrui; Gannett, Cara; Malapit, Christian A.; Hill, David E.; Vogt, David; Tang, Tianhua; Daley, Ryan A.; et al (May 2022, Nature)

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In Situ Kinetic Studies of Rh(II)-Catalyzed Asymmetric Cyclopropanation with Low Catalyst Loadings

https://doi.org/10.1021/acscatal.9b04595

Wei, Bo; Sharland, Jack C.; Lin, Patricia; Wilkerson-Hill, Sidney M.; Fullilove, Felicia A.; McKinnon, Sam; Blackmond, Donna G.; Davies, Huw M. (December 2019, ACS Catalysis)

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A General Protocol for Addressing Speciation of the Active Catalyst Applied to Ligand-Accelerated Enantioselective C(sp ³ )–H Bond Arylation

https://doi.org/10.1021/acscatal.8b00103

Hill, David E.; Pei, Qing-lan; Zhang, En-xuan; Gage, James R.; Yu, Jin-Quan; Blackmond, Donna G. (January 2018, ACS Catalysis)

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