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A critical spintronics challenge is to develop molecular wires that render efficiently spin-polarized currents. Interplanar torsional twisting, driven by chiral binucleating ligands in highly conjugated molecular wires, gives rise to large near-infrared rotational strengths. The large scalar product of the electric and magnetic dipole transition moments ( μ → i j ⋅ m → i j ), which are evident in the low-energy absorptive manifolds of these wires, makes possible enhanced chirality-induced spin selectivity–derived spin polarization. Magnetic-conductive atomic force microscopy experiments and spin-Hall devices demonstrate that these designs point the way to achieve high spin selectivity and large-magnitude spin currents in chiral materials.
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Roy, Partha Pratim ; Kundu, Sohang ; Valdiviezo, Jesús ; Bullard, George ; Fletcher, James T. ; Liu, Rui ; Yang, Shiun-Jr ; Zhang, Peng ; Beratan, David N. ; Therien, Michael J. ; et al ( , Journal of the American Chemical Society)