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Ekmekci, C. ; Cetin, M. ( , Conference on Neural Information Processing Systems (NeurIPS), Deep Inverse Workshop)
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Beldjoudi, Yassine ; Narayanan, Ashwin ; Roy, Indranil ; Pearson, Tyler J. ; Cetin, M. Mustafa ; Nguyen, Minh T. ; Krzyaniak, Matthew D. ; Alsubaie, Fehaid M. ; Wasielewski, Michael R. ; Stupp, Samuel I. ; et al ( , Journal of the American Chemical Society)
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Cetin, M. Mustafa ; Beldjoudi, Yassine ; Roy, Indranil ; Anamimoghadam, Ommid ; Bae, Youn Jue ; Young, Ryan M. ; Krzyaniak, Matthew D. ; Stern, Charlotte L. ; Philp, Douglas ; Alsubaie, Fehaid M. ; et al ( , Journal of the American Chemical Society)
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Cetin, M. Mustafa ; Shafiei‐Haghighi, Sara ; Chen, Jiazhen ; Zhang, Sheng ; Miller, Amanda C. ; Unruh, Daniel K. ; Casadonte, Jr, Dominick J. ; Lohr, Tracy L. ; Marks, Tobin J. ; Mayer, Michael F. ; et al ( , Journal of Polymer Science)
Abstract The syntheses of the 2,9‐dimesityl‐1,10‐phenanthroline (
dmesp ) metal complexes, [Cu(dmesp)(MeCN)]PF6(1 ), [Cu(dmesp)2]PF6(2 ), Fe(dmesp)Cl2(3 ), Co(dmesp)Cl2(4 ), Ni(dmesp)Cl2(5 ), Zn(dmesp)Cl2(6 ), Pd(dmesp)MeCl (7 ), Cu(dmesp)Cl (8 ), and Pd(dmesp)2Cl2(9 ), in good to high yields are described. These complexes were characterized by1H and13C NMR spectroscopy, HR–MS (ESI and/or APPI), and elemental analysis (CHN). The solid‐state structures of complexes1 –8 were determined by single‐crystal X‐ray analysis and their photophysical properties were also characterized. To demonstrate the versatility of this new platform, complexes3 –5 ,8 , and9 were employed in the catalytic oligomerization of ethylene using modified methyl aluminoxane (MMAO) as the cocatalyst, where Co(II) and Ni(II) complexes (4 and5 , respectively) were found to exhibit moderate selectivity for catalytic dimerization of ethylene to butenes over tri‐ or tetramerization. Complex8 is an effective catalyst of both the commonly encountered “click” reaction and amine arylation chemistries. Complexes6 and9 were found to be excellent catalysts for Friedel‐Crafts alkylation and Suzuki‐Miyaura coupling, respectively.