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Abstract Most organic semiconductors have closed-shell electronic structures, however, studies have revealed open-shell character emanating from design paradigms such as narrowing the bandgap and controlling the quinoidal-aromatic resonance of the π-system. A fundamental challenge is understanding and identifying the molecular and electronic basis for the transition from a closed- to open-shell electronic structure and connecting the physicochemical properties with (opto)electronic functionality. Here, we report donor-acceptor organic semiconductors comprised of diketopyrrolopyrrole and naphthobisthiadiazole acceptors and various electron-rich donors commonly utilized in constructing high-performance organic semiconductors. Nuclear magnetic resonance, electron spin resonance, magnetic susceptibility measurements, single-crystal X-ray studies, and computational investigations connect the bandgap, π-extension, structural, and electronic features with the emergence of various degrees of diradical character. This work systematically demonstrates the widespread diradical character in the classical donor-acceptor organic semiconductors and provides distinctive insights into their ground state structure-property relationship. 

We present a comparative study of the tribological properties of Pd-, Pt-, and Zr-based bulk metallic glasses (BMG-Pd, BMG-Pt, and BMG-Zr, respectively) under unlubricated conditions. In particular, micro-tribometry is utilized with a 52,100 steel ball, showing that BMG-Pt exhibits a significantly higher coefficient of friction (COF) (0.58 ± 0.08) when compared with BMG-Pd (0.30 ± 0.02) and BMG-Zr (0.20 ± 0.03). Topographical roughness on and off wear scars is characterized via atomic force microscopy (AFM), with results that do not correlate with the observed frictional behavior. On the other hand, scanning electron microscopy (SEM) is utilized to reveal contrasting wear mechanisms for the three samples: while BMG-Pd and BMG-Zr exhibit predominantly abrasive wear, there is evidence of adhesive wear on BMG-Pt. Consequently, the occurrence of adhesive wear emerges as a potential mechanism behind the observation of relatively high coefficients of friction on BMG-Pt, suggesting stronger interactions with steel when compared with the other BMG samples. 

Context.The nearby elliptical galaxy M87 contains one of only two supermassive black holes whose emission surrounding the event horizon has been imaged by the Event Horizon Telescope (EHT). In 2018, more than two dozen multi-wavelength (MWL) facilities (from radio toγ-ray energies) took part in the second M87 EHT campaign. Aims.The goal of this extensive MWL campaign was to better understand the physics of the accreting black hole M87*, the relationship between the inflow and inner jets, and the high-energy particle acceleration. Understanding the complex astrophysics is also a necessary first step towards performing further tests of general relativity. Methods.The MWL campaign took place in April 2018, overlapping with the EHT M87* observations. We present a new, contemporaneous spectral energy distribution (SED) ranging from radio to very high-energy (VHE)γ-rays as well as details of the individual observations and light curves. We also conducted phenomenological modelling to investigate the basic source properties. Results.We present the first VHEγ-ray flare from M87 detected since 2010. The flux above 350 GeV more than doubled within a period of ≈36 hours. We find that the X-ray flux is enhanced by about a factor of two compared to 2017, while the radio and millimetre core fluxes are consistent between 2017 and 2018. We detect evidence for a monotonically increasing jet position angle that corresponds to variations in the bright spot of the EHT image. Conclusions.Our results show the value of continued MWL monitoring together with precision imaging for addressing the origins of high-energy particle acceleration. While we cannot currently pinpoint the precise location where such acceleration takes place, the new VHEγ-ray flare already presents a challenge to simple one-zone leptonic emission model approaches, and it emphasises the need for combined image and spectral modelling. 

A<sc>bstract</sc> A measurement is performed of Higgs bosons produced with high transverse momentum (p_T) via vector boson or gluon fusion in proton-proton collisions. The result is based on a data set with a center-of-mass energy of 13 TeV collected in 2016–2018 with the CMS detector at the LHC and corresponds to an integrated luminosity of 138 fb⁻¹. The decay of a high-p_THiggs boson to a boosted bottom quark-antiquark pair is selected using large-radius jets and employing jet substructure and heavy-flavor taggers based on machine learning techniques. Independent regions targeting the vector boson and gluon fusion mechanisms are defined based on the topology of two quark-initiated jets with large pseudorapidity separation. The signal strengths for both processes are extracted simultaneously by performing a maximum likelihood fit to data in the large-radius jet mass distribution. The observed signal strengths relative to the standard model expectation are$$ {4.9}_{-1.6}^{+1.9} $$ ${4.9}_{-1.6}^{+1.9}$and$$ {1.6}_{-1.5}^{+1.7} $$ ${1.6}_{-1.5}^{+1.7}$for the vector boson and gluon fusion mechanisms, respectively. A differential cross section measurement is also reported in the simplified template cross section framework.