Search for: All records

Abstract Raman spectroscopy is a rapid, nondestructive analysis technique used in various scientific disciplines, including mineralogy, chemistry, materials science, and biology. The analysis of Raman spectra and the identification of specific substances in unknown samples can be complex and time-consuming due to the large database of Raman spectra. The Raman Match application was developed to simplify and automate the sample identification process through a search and match method. The application integrates the well-established RRUFF Raman database with the Python programming language. It provides a user-friendly graphical interface to load Raman spectra, identify and fit peaks, match peaks to the reference libraries, visualize the results, and generate publication-ready figures. The application offers a swift and automated method for mineral identification using Raman spectroscopy in laboratory and field settings and during planetary exploration missions to extraterrestrial environments with constraints on time and resources. 

Abstract Davemaoite (CaSiO3 perovskite) is considered the third most abundant phase in the pyrolytic lower mantle and the second most abundant phase in the subducted mid-ocean ridge basalt (MORB). During the partial melting of the pyrolytic upper mantle, incompatible titanium (Ti) becomes enriched in the basaltic magma, forming Ti-rich MORB. Davemaoite is considered an important Ti-bearing mineral in subducted slabs by forming a Ca(Si,Ti)O3 solid solution. However, the crystal structure and compressibility of Ca(Si,Ti)O3 perovskite solid solution at relevant pressure and temperature conditions had not been systematically investigated. In this study, we investigated the structure and equations of state of Ca(Si0.83Ti0.17)O3 and Ca(Si0.75Ti0.25)O3 perovskites at room temperature up to 82 and 64 GPa, respectively, by synchrotron X-ray diffraction (XRD). We found that both Ca(Si0.83Ti0.17)O3 and Ca(Si0.75Ti0.25)O3 perovskites have a tetragonal structure up to the maximum pressures investigated. Based on the observed data and compared to pure CaSiO3 davemaoite, both Ca(Si0.83Ti0.17)O3 and Ca(Si0.75Ti0.25)O3 perovskites are expected to be less dense up to the core-mantle boundary (CMB), and specifically ~1–2% less dense than CaSiO3 davemaoite in the pressure range of the transition zone (15–25 GPa). Our results suggest that the presence of Ti-bearing davemaoite phases may result in a reduction in the average density of the subducting slabs, which in turn promotes their stagnation in the lower mantle. The presence of low-density Ti-bearing davemaoite phases and subduction of MORB in the lower mantle may also explain the seismic heterogeneity in the lower mantle, such as large low shear velocity provinces (LLSVPs). 

The standard flare model, despite its success, is limited in comprehensively explaining the various processes involving nonthermal particles. One such missing ingredient is a detailed understanding of the various processes involved during the transport of accelerated electrons from their site of acceleration to different parts of the flare region. Here we use simultaneous radio and X-ray observations from the Expanded Owens Valley Solar Array and the Spectrometer/Telescope for Imaging X-rays on board the Solar Orbiter, respectively, from two distinct viewing perspectives, to study the electron transport processes. Through detailed spectral modeling of the coronal source using radio data and footpoint sources using X-ray spectra, we compare the nonthermal electron distribution at the coronal and footpoint sources. We find that the flux of the nonthermal electrons precipitated at the footpoint is an order of magnitude greater than that trapped in the looptop, consistent with earlier works that primarily used X-ray for their studies. In addition, we find that the electron spectral indices obtained from X-ray footpoints are significantly softer than the spectral hardness of the nonthermal electron distribution in the corona. We interpret these differences based on transport effects and the difference in sensitivity of microwave and X-ray observations to different regimes of electron energies. Such an understanding is crucial for leveraging different diagnostic methods of nonthermal electrons simultaneously to achieve a more comprehensive understanding of the electron acceleration and transport processes of solar flares. 

Abstract Incorporation of ferric iron in mantle silicates stabilizes different crystal structures and changes phase transition conditions, thus impacting seismic wave speeds and discontinuities. In MgSiO3-Fe2O3 mixtures, recent experiments indicate the coexistence of fully oxidized iron-rich (Mg0.5Fe0.53+)(Fe0.53+Si0.5)O3 with Fe-poor silicate (wadsleyite or bridgmanite) and stishovite at 15 to 27 GPa and 1773 to 2000 K, conditions relevant to subducted lithosphere in the Earth’s transition zone and uppermost lower mantle. X-ray diffraction measurements show that (Mg0.5Fe0.53+)(Fe0.53+Si0.5)O3 recovered from these conditions adopts the R3c LiNbO3-type structure, which transforms to the bridgmanite structure again between 18.3 GPa and 24.7 GPa at 300 K. Diffraction observations are used to obtain the equation of state of the LiNbO3-type phase up to 18.3 GPa. These observations combined with multi-anvil experiments suggest that the stable phase of (Mg0.5Fe0.53+)(Fe0.53+Si0.5)O3 is bridgmanite at 15-27 GPa, which transforms on decompression to LiNbO3-type structure. Our calculation revealed that ordering of the ferric ion reduces the kinetic energy barrier of the transition between (Mg0.5Fe0.53+)(Fe0.53+Si0.5)O3 LiNbO3 structure and bridgmanite relative to the MgSiO3 akimotoite-bridgmanite system. Dense Fe3+-rich bridgmanite structure is thus stable at substantially shallower depths than MgSiO3 bridgmanite and would promote subduction. 

ABSTRACT We report striking Doppler velocity gradients observed during the well-observed 2017 September 10 solar flare, and argue that they are consistent with the presence of an above-the-looptop termination shock beneath the flare current sheet. Observations from the Hinode Extreme-ultraviolet Imaging Spectrometer measure plasma sheet Doppler shifts up to 35 km s−1 during the late-phase of the event. By comparing these line-of-sight flows with plane-of-sky (POS) measurements, we calculate total velocity downflows of 200+ km s−1, orientated ≈6–10° out of the POS. The observed velocities drop rapidly at the base of the hot plasma sheet seen in extreme ultraviolet, consistent with simulated velocity profiles predicted by our 2.5D magnetohydrodynamics model that features a termination shock at the same location. Finally, the striking velocity deceleration aligns spatially with the suppression of Fe xxiv non-thermal velocities, and a 35–50 keV hard X-ray looptop source observed by the Reuven Ramaty High Energy Solar Spectroscopic Imager. Together, these observations are consistent with the presence of a possible termination shock within the X8.2-class solar flare. 

Externally heated diamond anvil cells provide a stable and uniform thermal environment, making them a versatile device to simultaneously generate high-pressure and high-temperature conditions in various fields of research, such as condensed matter physics, materials science, chemistry, and geosciences. The present study features the Externally Heated Diamond ANvil Cell Experimentation (EH-DANCE) system, a versatile configuration consisting of a diamond anvil cell with a customized microheater for stable resistive heating, bidirectional pressure control facilitated by compression and decompression membranes, and a water-cooled enclosure suitable for vacuum and controlled atmospheres. This integrated system excels with its precise control of both pressure and temperature for mineral and materials science research under extreme conditions. We showcase the capabilities of the system through its successful application in the investigation of the melting temperature and thermal equation of state of high-pressure ice-VII at temperatures up to 1400 K. The system was also used to measure the elastic properties of solid ice-VII and liquid H2O using Brillouin scattering and Raman spectra of carbonates using Raman spectroscopy, highlighting the potential of the EH-DANCE system in high-pressure research.