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Today, the most taxonomically rich bivalve clade is Imparidentia. However, 300 million years ago, Imparidentia's sister clade, Anomalodesmata, was dominant among marine bivalves, while Imparidentia was much less diverse. Both clades are ecologically diverse but infaunal suspension-feeding is the dominant mode of life in each. When taxonomic diversity and morphological disparity are plotted through time for each clade, Imparidentia diversified faster in the Mesozoic than Anomalodesmata until the K/Pg boundary, when the extinction event interrupts the pattern, and both clades then diversified in parallel through the Cenozoic. In this paper, I test the hypothesis that life mode has an effect on morphological disparification and taxonomic diversification, that by ecologically separating themselves from the dominant infaunal suspension-feeding mode, some ‘divergent’ anomalodesmatan lineages may have been able to free themselves from direct competition with imparidents and once more start to rise in morphological and taxonomic diversity. During the Cenozoic, morphological disparity of divergent Anomalodesmata does increase compared to their infaunal suspension-feeding relatives. However, taxonomic diversity does not differ between divergent and infaunal suspension-feeding anomalodesmatan lineages. This suggests that functional partitioning drives morphological disparification, but not taxonomic diversification.

Solid-state electrolytes (SSEs) are challenged by complex interfacial chemistry and poor ion transport through the interfaces they form with battery electrodes. Here, we investigate a class of SSE composed of micrometer-sized lithium oxide (Li₂O) particles dispersed in a polymerizable 1,3-dioxolane (DOL) liquid. Ring-opening polymerization (ROP) of the DOL by Lewis acid salts inside a battery cell produces polymer-inorganic hybrid electrolytes with gradient properties on both the particle and battery cell length scales. These electrolytes sustain stable charge-discharge behavior in Li||NCM811 and anode-free Cu||NCM811 electrochemical cells. On the particle length scale, Li₂O retards ROP, facilitating efficient ion transport in a fluid-like region near the particle surface. On battery cell length scales, gravity-assisted settling creates physical and electrochemical gradients in the hybrid electrolytes. By means of electrochemical and spectroscopic analyses, we find that Li₂O particles participate in a reversible redox reaction that increases the effective CE in anode-free cells to values approaching 100%, enhancing battery cycle life.

High latitude upper atmospheric inter‐hemispheric asymmetry (IHA) tends to be enhanced during geomagnetic storms, which may be due to the complex spatiotemporal changes and magnitude modifications in field aligned currents (FACs) and particle precipitation (PP). However, the relative contribution of FACs and PP to IHA in high‐latitude forcing and energy is not well understood. The IHA during the 2015 St. Patrick’s Day storm has been investigated using the global ionosphere thermosphere model (GITM), driven by FACs from the Active Magnetosphere and Planetary Electrodynamics Response Experiment (AMPERE) and PP from the Assimilative Mapping of Ionospheric Electrodynamics (AMIE). A comprehensive study of the (a) relative contributions of FACs and PP to electric potential and Joule heating and (b) sensitivity of electric potential and Joule heating to the changes in magnitude and distribution of FACs and PP is presented. The results indicate that FACs lead to larger potential and Joule heating changes compared with PP. The spatial variations of potential and Joule heating are also affected by variation in FACs. As for asymmetric magnitude and distribution, it is found that electric potential and Joule heating are more sensitive to changes in the distribution of FACs and PP than the magnitude of FACs and PP. A new spatial asymmetry index (SAI) is introduced, which reveals spatial asymmetric details that are often overlooked by previous studies. This sensitivity study reveals the relative contributions in high‐latitude forcing and emphasizes the importance of obtaining accurate FACs and PP in both hemispheres.

Rechargeable metal–air batteries operated in ambient air fail as a result of complex anode surface reactions. Interphases composed of metallic In protect Li anodes, enabling Li–air batteries to operate in ambient air.

Inter-hemispheric asymmetry (IHA) in Earth’s ionosphere–thermosphere (IT) system can be associated with high-latitude forcing that intensifies during storm time, e.g., ion convection, auroral electron precipitation, and energy deposition, but a comprehensive understanding of the pathways that generate IHA in the IT is lacking. Numerical simulations can help address this issue, but accurate specification of high-latitude forcing is needed. In this study, we utilize the Active Magnetosphere and Planetary Electrodynamics Response Experiment-revised fieldaligned currents (FACs) to specify the high-latitude electric potential in the Global Ionosphere and Thermosphere Model (GITM) during the October 8–9, 2012, storm. Our result illustrates the advantages of the FAC-driven technique in capturing high-latitude ion drift, ion convection equatorial boundary, and the storm-time neutral density response observed by satellite. First, it is found that the cross-polar-cap potential, hemispheric power, and ion convection distribution can be highly asymmetric between two hemispheres with a clear B_ydependence in the convection equatorial boundary. Comparison with simulation based on mirror precipitation suggests that the convection distribution is more sensitive to FAC, while its intensity also depends on the ionospheric conductance-related precipitation. Second, the IHA in the neutral density response closely follows the IHA in the total Joule heating dissipation with a time delay. Stronger Joule heating deposited associated with greater high-latitude electric potential in the southern hemisphere during the focus period generates more neutral density as well, which provides some evidences that the high-latitude forcing could become the dominant factor to IHAs in the thermosphere when near the equinox. Our study improves the understanding of storm-time IHA in high-latitude forcing and the IT system.