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The sulfur chemistry of (162173) Ryugu particles can be a powerful tracer of molecular cloud chemistry and small body processes, but it has not been well explored. We report identification of organosulfurs and a sulfate grain in two Ryugu particles, A0070 and A0093. The sulfate grain shows oxygen isotope ratios (δ¹⁷O = −11.0 ± 4.3 per mil, δ¹⁸O = −7.8 ± 2.3 per mil) that are akin to silicates in Ryugu but exhibit mass-independent sulfur isotopic fractionation (Δ³³S = +5 ± 2 per mil). A methionine-like coating on the sulfate grain is isotopically anomalous (δ¹⁵N = +62 ± 2 per mil). Both the sulfate and organosulfurs can simultaneously form and survive during aqueous alteration within Ryugu’s parent body, under reduced conditions, low temperature, and a pH >7 in the presence of N-rich organic molecules. This work extends the heliocentric zone where anomalous sulfur, formed by selective photodissociation of H₂S gas in the molecular cloud, is found. 

ABSTRACT There is a wealth of evidence to suggest that planetary systems can survive beyond the main sequence. Most commonly, white dwarfs are found to be accreting material from tidally disrupted asteroids, whose bulk compositions are reflected by the metals polluting the stellar photospheres. While many examples are known, most lack the deep, high-resolution data required to detect multiple elements, and thus characterize the planetesimals that orbit them. Here, spectra of seven DZ white dwarfs observed with Keck High Resolution Echelle Spectrometer (HIRES) are analysed, where up to nine metals are measured per star. Their compositions are compared against those of Solar system objects, working in a Bayesian framework to infer or marginalize over the accretion history. All of the stars have been accreting primitive material, similar to chondrites, with hints of a Mercury-like composition at one star. The most polluted star is observed several Myr after its last major accretion episode, in which a Moon-sized object met its demise.