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Nitrate (NO3) pollution in groundwater, caused by various factors both natural and synthetic, contributes to the decline of human health and well-being. Current techniques used for nitrate detection include spectroscopic, electrochemical, chromatography, and capillary electrophoresis. It is highly desired to develop a simple cost-effective alternative to these complex methods for nitrate detection. Therefore, a real-time poly (3,4-ethylenedioxythiophene) (PEDOT)-based sensor for nitrate ion detection via electrical property change is introduced in this study. Vapor phase polymerization (VPP) is used to create a polymer thin film. Variations in specific parameters during the process are tested and compared to develop new insights into PEDOT sensitivity towards nitrate ions. Through this study, the optimal fabrication parameters that produce a sensor with the highest sensitivity toward nitrate ions are determined. With the optimized parameters, the electrical resistance response of the sensor to 1000 ppm nitrate solution is 41.79%. Furthermore, the sensors can detect nitrate ranging from 1 ppm to 1000 ppm. The proposed sensor demonstrates excellent potential to detect the overabundance of nitrate ions in aqueous solutions in real time.more » « less
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Boon-Chong Seet (Ed.)In this paper, we investigate the application of using software-defined radio (SDR) and surface acoustic wave (SAW) device for wireless measurement of the response of in situ sensors. SDR uses software to realize different communication functions. After collecting the magnitude and phase of the response at discrete frequencies, we apply inverse Fourier transform to analyze the time domain responses which, in turn, allows for monitoring the changes of the response of the in situ sensor. We employ microwave signal flow graph concepts to improve the quality of the received signals. Comparing the normalized results obtained by SDR with those obtained from a commercial vector network analyzer (VNA), we demonstrate that the results are sufficiently close, and the SDR-based experiments can provide satisfactory measurement of the in-situ sensors. The objective is to eventually employ this wireless measurement system for soil nutrient sensing.more » « less
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New York City’s food distribution system is among the largest in the United States. Food is transported by trucks from twelve major distribution centers to the city’s point-of-sale locations. Trucks consume large amounts of energy and contribute to large amounts of greenhouse gas emissions. Therefore, there is interest to increase the efficiency of New York City’s food distribution system. The Gowanus district in New York City is undergoing rezoning from an industrial zone to a mix residential and industrial zone. It serves as a living lab to test new initiatives, policies, and new infrastructure for electric vehicles. We analyze the impact of electrification of food-distribution trucks on greenhouse gas emissions and electricity demand in this paper. However, such analysis faces the challenges of accessing available and granular data, modeling of demands and deliveries that incorporate logistics and inventory management of different types of food retail stores, delivery route selection, and delivery schedule to optimize food distribution. We propose a framework to estimate truck routes for food delivery at a district level. We model the schedule of food delivery from a distribution center to retail stores as a vehicle routing problem using an optimization solver. Our case study shows that diesel trucks consume 300% more energy than electric trucks and generate 40% more greenhouse gases than diesel trucks for food distribution in the Gowanus district.more » « less