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Phase transformations are widely invoked as a source of rheological weakening during subduction, continental collision, mantle convection and various other geodynamic phenomena. However, despite more than half a century of research, the likelihood and magnitude of such weakening in nature remain poorly constrained. Here we use experiments performed on a synchrotron beamline to reveal transient weakening of up to three orders of magnitude during the polymorphic quartz to coesite (SiO2) and olivine to ringwoodite (Fe2SiO4) phase transitions. Weakening becomes increasingly prominent as the transformation outpaces deformation. We suggest that this behaviour is broadly applicable among silicate minerals undergoing first-order phase transitions and examine the likelihood of weakening due to the olivine-spinel, (Mg,Fe)2SiO4, transformation during subduction. Modelling suggests that cold, wet slabs are most susceptible to transformational weakening, consistent with geophysical observations of slab stagnation in the mantle transition zone beneath the western Pacific. Our study highlights the importance of incorporating transformational weakening into geodynamic simulations and provides a quantitative basis for doing so. 

We present the results of high-temperature (900°C), high-pressure (200 MPa) deformation experiments that identify the processes and deformation conditions leading to melt migration in crystal-rich mushes. This study is relevant to transport of magmas in transcrustal magma reservoirs. Experimental samples comprise juxtaposed pieces of soda-lime glass and densified mixtures of borosilicate glass and quartz sand, which, at elevated temperatures and pressures, have melt and shear viscosities similar to natural silicate melts and crystal-rich mushes. The synthetic mushes have crystal fractions of 0.60 to 0.83. Samples were deformed in torsion at shear strain rates of 10-5 to 10-4 s-1 to shear strains up to 2.7. Image analysis of experimental samples shows melt migrates into the mush during shear. In mushes with crystal fractions ≥ 0.75 shearing causes melt-filled mm-scale dikes to form and propagate into the mush. To our knowledge, these features are the first dikes formed in high-temperature, high-pressure deformation experiments. Dike formation results from shear-induced dilation, which causes the mush to become underpressurized relative to the melt, at an estimated pressure differential of 10 MPa. Experimental conditions indicate shear-induced dilation and diking occur while the mush is still viscous (i.e., Weissenberg number < 10-2). We apply our results to Soufrière Hills Volcano (Montserrat, West Indies) and use our analysis to predict the deformation conditions that would lead to diking and rapid, voluminous melt migration in that active volcanic system. 

Abstract Dislocation‐based dissipation mechanisms potentially control the viscoelastic response of Earth's upper mantle across a variety of geodynamic contexts, including glacial isostatic adjustment, postseismic creep, and seismic‐wave attenuation. However, there is no consensus on which dislocation‐based, microphysical process controls the viscoelastic behavior of the upper mantle. Although both intergranular (plastic anisotropy) and intragranular (backstress) mechanisms have been proposed, there is currently insufficient laboratory data to discriminate between those mechanisms. Here, we present the results of forced‐oscillation experiments in a deformation‐DIA apparatus at confining pressures of 3–7 GPa and temperatures of 298–1370 K. Our experiments tested the viscoelastic response of polycrystalline olivine—the main constituent of the upper mantle—at stress amplitudes from 70 to 2,800 MPa. Mechanical data are complemented by microstructural analyses of grain size, crystallographic preferred orientation, and dislocation density. We observe amplitude‐ and frequency‐dependent attenuation and modulus relaxation and find that numerical solutions of the backstress model match our results well. Therefore, we argue that interactions among dislocations, rather than intergranular processes (e.g., plastic anisotropy or grain boundary sliding), control the viscoelastic behavior of polycrystalline olivine in our experiments. In addition, we present a linearized version of the constitutive equations of the backstress model and extrapolate it to conditions typical of seismic‐wave propagation in the upper mantle. Our extrapolation demonstrates that the backstress model can explain the magnitude of seismic‐wave attenuation in the upper mantle, although some modification is required to explain the weak frequency dependence of attenuation observed in nature and in previous experimental work. 

The strength of lithospheric plates is a central component of plate tectonics, governed by brittle processes in the shallow portion of the plate and ductile behavior in the deeper portion. We review experimental constraints on ductile deformation of olivine, the main mineral in the upper mantle and thus the lithosphere. Olivine deforms by four major mechanisms: low-temperature plasticity, dislocation creep, dislocation-accommodated grain-boundary sliding (GBS), and diffusion-accommodated grain-boundary sliding (diffusion creep). Deformation in most of the lithosphere is dominated by GBS, except in shear zones—in which diffusion creep dominates—and in the brittle-ductile transition—in which low-temperature plasticity may dominate. We find that observations from naturally deformed rocks are consistent with extrapolation of the experimentally constrained olivine flow laws to geological conditions but that geophysical observations predict a weaker lithosphere. The causes of this discrepancy are unresolved but likely reside in the uncertainty surrounding processes in the brittle-ductile transition, at which the lithosphere is strongest. ▪ Ductile deformation of the lithospheric mantle is constrained by experimental data for olivine. ▪ Olivine deforms by four major mechanisms: low-temperature plasticity, dislocation creep, dislocation-accommodated grain-boundary sliding, and diffusion creep. ▪ Observations of naturally deformed rocks are consistent with extrapolation of olivine flow laws from experimental conditions. ▪ Experiments predict stronger lithosphere than geophysical observations, likely due to gaps in constraints on deformation in the brittle-ductile transition. 

Abstract We conducted experiments to study melt migration in crystal‐rich mushes, with application to magma ascent within transcrustal magma reservoirs. Mushes with crystal volume fractions of 0.59–0.83 were prepared by hot‐pressing crushed borosilicate glass mixed with different proportions of quartz sand particles. Each experimental sample comprises stacked disks of mush and soda‐lime glass, a proxy for crystal‐free magma. Samples were subjected to confining pressures of 100–300 MPa and a temperature of 900°C (above the glass transition temperatures of the borosilicate and soda‐lime glasses) for up to 6 h. The bottom and circumference of the mush and soda lime disks experience the confining pressure, but the top of the mush disks is at room pressure, resulting in a pore‐pressure gradient across the mush layer. Following cooling and decompression, we determined the area fraction and morphology of soda‐lime melt that migrated into the mush layer during experiments. Melt fraction is more strongly correlated to crystal fraction than pore‐pressure gradient, increasing with crystal fraction before sharply decreasing as crystal fractions exceed 0.8. This change at 0.8 coincides with the transition from crystals in the mush moving during soda‐lime migration to crystals forming a continuous rigid network. In our experiments, melt migration occurred by viscous fingering, but near the mobile‐to‐rigid transition, melt migration is enhanced by additional capillary action. Our results indicate that magma migration may peak when rigid mushes “unlock” to become mobile. This transition may mark an increase in magma migration, a potential precursor to volcanic unrest and eruption. 

Constraints on the state of stress in the lithosphere are fundamental to understanding a breadth of geological phenomena. Paleo-stresses are generally estimated using microstructural elements for which there are experimentally calibrated relationships with applied stress, with an emphasis on recrystallised grain-size piezometers. However, it is often difficult to clearly distinguish newly recrystallised grains from the relict matrix. Furthermore, these grain-size piezometers are only applicable to rocks consisting of a single mineral. An alternative proxy for paleo-stress in polymineralic rocks is the average subgrain size. Unfortunately, estimates of subgrain size differ significantly among different measurement methods, and therefore, piezometers must be individually calibrated for the method used. Existing subgrain-size piezometers are based on calibrations using optical or transmission electron microscopy. We use electron backscatter diffraction (EBSD), a common method of subgrain-boundary characterisation, to calibrate subgrain-size piezometers for both olivine and quartz. To test the application of our olivine subgrain-size piezometer to polymineralic rocks, we deformed synthetic mixtures of olivine and orthopyroxene. Experiments were conducted using a Deformation-DIA apparatus at beamline 6BM-B Advanced Photon Source, Argonne National Laboratory. These experiments offer the unique possibility of simultaneously deforming the sample and measuring the average stresses within each phase using X-ray diffraction, before applying subgrain-size piezometry to the recovered samples. The results provide tests of (1) the manner in which stress is partitioned between phases, (2) whether the stresses measured in each phase by X-ray diffraction are comparable to those estimated by subgrain-size piezometry, and (3) whether stresses from subgrain piezometry can be used to estimate the macroscopic average applied stress. Stresses estimated from X-ray diffraction agree well with those made from subgrain-size piezometry in both monomineralic and polymineralic samples. In harzburgites, average stresses are similar in both phases and indicate that in this system, subgrain-size piezometric measurements from a single phase can be used to estimate the bulk stress.